Dataset Information

Cobalta-Electrocatalyzed C-H Activation in Biomass-Derived Glycerol: Powered by Renewable Wind and Solar Energy.

ABSTRACT: Aqueous glycerol was identified as a renewable reaction medium for metalla-electrocatalyzed C-H activation powered by sustainable energy sources. The renewable solvent was employed for cobalt-catalyzed C-H/N-H functionalizations under mild conditions. The cobalta-electrocatalysis manifold occurred with high levels of chemo- and positional selectivity and allowed for electrochemical C-H activations with broad substrate scope. The resource economy of this strategy was considerably substantiated by the direct use of renewable solar and wind energy.

SUBMITTER: Meyer TH

PROVIDER: S-EPMC7065255 | biostudies-literature | 2020 Feb

REPOSITORIES: biostudies-literature

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Publications

Cobalta-Electrocatalyzed C-H Activation in Biomass-Derived Glycerol: Powered by Renewable Wind and Solar Energy.

Meyer Tjark H TH Chesnokov Gleb A GA Ackermann Lutz L

ChemSusChem 20200130 4

Aqueous glycerol was identified as a renewable reaction medium for metalla-electrocatalyzed C-H activation powered by sustainable energy sources. The renewable solvent was employed for cobalt-catalyzed C-H/N-H functionalizations under mild conditions. The cobalta-electrocatalysis manifold occurred with high levels of chemo- and positional selectivity and allowed for electrochemical C-H activations with broad substrate scope. The resource economy of this strategy was considerably substantiated by ...[more]

PMID: 31917522

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Project description:Recent national strategic plans in China have set renewable energy targets for rural household energy programs, including those that advance the production of densified biomass fuels (e.g. pellets, briquettes) for use in household cooking and heating stoves. There is presently very little information on potential barriers to the successful development of densified biomass for household cooking and heating in China, but such knowledge may be informative in settings that aim to replace unprocessed coal and other polluting fuels with renewable, cleaner-burning energy sources. We designed a case study to coordinate data-gathering efforts at rural field sites in southwestern Sichuan province and northeastern Jilin and Heilongjiang provinces, where production of densified biomass fuels is under development for household end-users. We conducted interviews with factory personnel, local administrative leaders, and sector experts involved in the production and distribution of densified fuel, including pellets and briquettes, for household use. Results from our qualitative textual data analysis yielded several recommendations for improving development of densified biomass fuels for household end-use. These included reducing heterogeneity of feedstocks, increasing financial support for operational costs (e.g. collection, transport, and storage of raw materials; storage and distribution of final products), improving household perceptions of and subsequent demand for densified biomass fuels, and increasing enforcement of national and provincial policies banning the use of coal and open-field biomass burning. Collection and storage of raw materials and the final densified fuel product were consistently noted as critical challenges to scaling up production at all three sites. Finally, the perspectives of factory managers and local village administrators that we present also indicated that production of densified biomass fuels would most likely be more successful and reproducible in places where national-level policies are viewed as obligatory.

Dataset Information

Cobalta-Electrocatalyzed C-H Activation in Biomass-Derived Glycerol: Powered by Renewable Wind and Solar Energy.

Publications

Cobalta-Electrocatalyzed C-H Activation in Biomass-Derived Glycerol: Powered by Renewable Wind and Solar Energy.

Similar Datasets

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