Ontology highlight
ABSTRACT:
SUBMITTER: Thiess T
PROVIDER: S-EPMC7078994 | biostudies-literature | 2020 Mar
REPOSITORIES: biostudies-literature
Chemistry (Weinheim an der Bergstrasse, Germany) 20200221 13
Several bis(dimethylamino)-substituted 1,4-diaza-2,3-diborinines (DADBs) were synthesized with variable substituents at the backbone nitrogen atoms. By reaction with HCl or BX<sub>3</sub> (X=Br, I), these species were successfully converted into their synthetically more useful halide congeners. The high versatility of the generated B-X bonds in further functionalization reactions at the boron centers was demonstrated by means of salt elimination (MeLi) and commutation (NMe<sub>2</sub> DADBs) rea ...[more]