Ontology highlight
ABSTRACT:
SUBMITTER: Raman N
PROVIDER: S-EPMC7088128 | biostudies-literature | 2019 Oct
REPOSITORIES: biostudies-literature
Raman Narayanan N Maisel Sven S Grabau Mathias M Taccardi Nicola N Debuschewitz Jonas J Wolf Moritz M Wittkämper Haiko H Bauer Tanja T Wu Mingjian M Haumann Marco M Papp Christian C Görling Andreas A Spiecker Erdmann E Libuda Jörg J Steinrück Hans-Peter HP Wasserscheid Peter P
ACS catalysis 20190906 10
Our contribution demonstrates that rhodium, an element that has barely been reported as an active metal for selective dehydrogenation of alkanes becomes a very active, selective, and robust dehydrogenation catalyst when exposed to propane in the form of single atoms at the interface of a solid-supported, highly dynamic liquid Ga-Rh mixture. We demonstrate that the transition to a fully liquid supported alloy droplet at Ga/Rh ratios above 80, results in a drastic increase in catalyst activity wit ...[more]