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A redetermination of the crystal structure of the mannitol complex NH4[Mo2O5(C6H11O6)]·H2O: hydrogen-bonding scheme and Hirshfeld surface analysis.

ABSTRACT: The redetermined structure [for the previous study, see: Godfrey & Waters (1975 ?). Cryst. Struct. Commun. 4, 5-8] of ammonium ?-oxido-?-[1,5,6-tri-hydroxy-hexane-2,3,4-tris-(olato)]bis-[dioxidomolybdenum(V)] monohydrate, NH4[Mo2(C6H11O6)O5]·H2O, was obtained from an attempt to prepare a glutamic acid complex from the [Co2Mo10H4O38]6- anion. Subsequent study indicated the complex arose from a substantial impurity of mannitol in the glutamic acid sample used. All hydrogen atoms have been located in the present study and the packing displays N-H?O, O-H?O and C-H?O hydrogen bonds. A Hirshfeld surface analysis was also performed.

SUBMITTER: Mirzaei M 

PROVIDER: S-EPMC7133038 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature

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A redetermination of the crystal structure of the mannitol complex NH<sub>4</sub>[Mo<sub>2</sub>O<sub>5</sub>(C<sub>6</sub>H<sub>11</sub>O<sub>6</sub>)]·H<sub>2</sub>O: hydrogen-bonding scheme and Hirshfeld surface analysis.

Mirzaei Masoud M   Tahmasebi Morteza M   Mague Joel T JT  

Acta crystallographica. Section E, Crystallographic communications 20200310 Pt 4

The redetermined structure [for the previous study, see: Godfrey & Waters (1975 ▸). <i>Cryst. Struct. Commun.</i> <b>4</b>, 5-8] of ammonium μ-oxido-μ-[1,5,6-tri-hydroxy-hexane-2,3,4-tris-(olato)]bis-[dioxidomolybdenum(V)] monohydrate, NH<sub>4</sub>[Mo<sub>2</sub>(C<sub>6</sub>H<sub>11</sub>O<sub>6</sub>)O<sub>5</sub>]·H<sub>2</sub>O, was obtained from an attempt to prepare a glutamic acid complex from the [Co<sub>2</sub>Mo<sub>10</sub>H<sub>4</sub>O<sub>38</sub>]<sup>6-</sup> anion. Subsequent  ...[more]

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