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Influence of pore structure on humidity parameters of cement-polymer mortars contaminated with filamentous fungi.

ABSTRACT: Mineral building materials are porous materials. The volume of pores connected is the active volume of pores or the effective volume. The volume of all pores is the total volume of the pores. The properties of the individual pores are different. Their dimensions and shape can influence the properties of materials. Materials are modified with different admixtures to improve their properties. However, additives or admixtures can cause corrosion. Although building materials do not provide food for microorganisms, they are very often inhabited by them. As a result of their presence and the action of metabolic products, biodeterioration occurs. One of the products of metabolism is water. In this paper we investigated how the modified structure of biodeterioration caused by mould fungi affects the moisture content of cement-polymer mortar with the admixture of polysiloxane latex.

SUBMITTER: Stanaszek-Tomal E

PROVIDER: S-EPMC7145099 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Core-Shell Morphology of Redispersible Powders in Polymer-Cement Waterproof Mortars.

Project description:Redispersible powders based on soft core-hard shell polymer particles can be used as additives in polymer-cement mortars. The role of this morphology on the spray-drying production of these powders and on the crack-bridging properties of the corresponding cement-based membranes is investigated. Different polymer latexes at high solid content with varied core-shell ratio, shell thickness and chemical composition (hardness) were prepared from styrene and 2-ethylhexyl acrylate monomers via semi-batch emulsion polymerization. The latexes were characterized in terms of size, composition, and glass transition temperature (T g ), and spray-dried to obtain redispersible polymer powders (RPPs) using poly (vinyl alcohol) and limestone powder as anti-caking agents. The polymer powders were mixed with a mortar mixture and redispersed in water to produce cement-based membranes, which were tested for crack-bridging properties at different temperatures. The results showed that it was not possible to spray-dry a dispersion of homogeneous polymer particles with T g of -25 ∘ C, unless these particles are protected by much harder (high T g ) shell. In particular, it was observed that a thicker shell improved the spray-ability, but lowered the crack-bridging properties of the produced membrane. A trade-off between these two was revealed to be the key for the optimal design of the polymer nanoparticles, as proven by the systematic study of the core-shell morphology reported in this work. The best compromise was shown to consist of particles larger than 300 nm, shell thickness of about 5 nm, and core-shell ratio of 97%, with styrene content in the shell not larger than 80% to avoid excessive hydrophobicity.

| S-EPMC6403678 | biostudies-literature

Influence of Granulometry on Thermal and Mechanical Properties of Cement Mortars Containing Expanded Perlite as a Lightweight Aggregate.

Project description:This research aims at clarifying the influence of the granulometry of expanded perlite, on the thermal conductivity, structural strength, density, and water absorption of lightweight mortars. Three original perlite gradations have been obtained and three pairs of twin test mortars have been tested with those gradations. SEM tests have also been run to clarify the interaction, at a microscopic level, between the expanded perlite and the cement grouting. The results indicate that the mere manipulation of the granulometry may have a considerable and very beneficial effect on the mixture's properties, such as thermal conductivity and water absorption.

| S-EPMC6926826 | biostudies-literature

Radiological Characteristics of Carbonated Portland Cement Mortars Made with GGBFS

Project description:The objective of this study is to assess whether the carbonation process can modify the physicochemical characteristics of the natural radionuclides of the three natural radioactive series, together with 40K. Three mortar specimens with different percentages of ground granulated blast-furnace slag (GGBFS), cured under water for 1, 3, 7, 14, or 28 days, were subjected to a natural carbonation process. Activity concentrations for the solid and ground mortars were determined by gamma spectrometry and by radiochemical separation of isotopic uranium. The novelty of this paper relies principally on the study we have carried out, for the first time, of the radiological characteristics of carbonated Portland cement mortars. It was found that the chemical properties of the 3 mortar specimens were not affected by the carbonation process, with particular attention placed on uranium (238U, 235U, and 234U), the activity concentrations of which were equivalent to the 226Ra results and ranged from 5.5 ± 1.6 Bq kg−1 to 21.4 ± 1.2 Bq kg−1 for the 238U. The average activity concentrations for the 3 types of mortars were lower than 20.1 Bq kg−1, 14.5 Bq kg−1, and 120.2 Bq kg−1 for the 226Ra, 232Th (212Pb), and 40K, respectively. Annual effective dose rates were equivalent to the natural background of 0.024 mSv. In addition, it was observed that the variation rate for the 222Rn emanation was due primarily to the Portland cement hydration and not due to the pore size redistribution as a consequence of the carbonation process. This research will provide new insights into the potential radiological risk from carbonated cement-based materials. Moreover, the assessment that is presented in this study will convey valuable information for future research that will explore the activity concentration of building materials containing NORM materials.

| S-EPMC9100595 | biostudies-literature

CO2 Curing Efficiency for Cement Paste and Mortars Produced by a Low Water-to-Cement Ratio.

Project description:Curing by CO2 is a way to utilize CO2 to reduce greenhouse gas emissions. Placing early-age cement paste in a CO2 chamber or pressure vessel accelerates its strength development. Cement carbonation is attributed to the quickened strength development, and CO2 uptake can be quantitatively evaluated by measuring CO2 gas pressure loss in the pressure vessel. A decrease in CO2 gas pressure is observed with all cement pastes and mortar samples regardless of the mix proportion and the casting method; one method involves compacting a low water-to-cement ratio mix, and the other method comprises a normal mix consolidated in a mold. The efficiency of the CO2 curing is superior when a 20% concentration of CO2 gas is supplied at a relative humidity of 75%. CO2 uptake in specimens with the same CO2 curing condition is different for each specimen size. As the specimen scale is larger, the depth of carbonation is smaller. Incorporating colloidal silica enhances the carbonation as well as the hydration of cement, which results in contributing to the increase in the 28-day strength.

| S-EPMC7503678 | biostudies-literature

Role of autochthonous filamentous fungi in bioremediation of a soil historically contaminated with aromatic hydrocarbons.

Project description:Nine fungal strains isolated from an aged and heavily contaminated soil were identified and screened to assess their degradative potential. Among them, Allescheriella sp. strain DABAC 1, Stachybotrys sp. strain DABAC 3, and Phlebia sp. strain DABAC 9 were selected for remediation trials on the basis of Poly R-478 decolorization associated with lignin-modifying enzyme (LME) production. These autochthonous fungi were tested for the abilities to grow under nonsterile conditions and to degrade various aromatic hydrocarbons in the same contaminated soil. After 30 days, fungal colonization was clearly visible and was confirmed by ergosterol determination. In spite of subalkaline pH conditions and the presence of heavy metals, the autochthonous fungi produced laccase and Mn and lignin peroxidases. No LME activities were detected in control microcosms. All of the isolates led to a marked removal of naphthalene, dichloroaniline isomers, o-hydroxybiphenyl, and 1,1'-binaphthalene. Stachybotrys sp. strain DABAC 3 was the most effective isolate due to its ability to partially deplete the predominant contaminants 9,10-anthracenedione and 7H-benz[DE]anthracen-7-one. A release of chloride ions was observed in soil treated with either Allescheriella sp. strain DABAC 1 or Stachybotrys sp. strain DABAC 3, suggesting the occurrence of oxidative dehalogenation. The autochthonous fungi led to a significant decrease in soil toxicity, as assessed by both the Lepidium sativum L. germination test and the Collembola mortality test.

| S-EPMC1352206 | biostudies-literature

filamentous fungi

Project description:fungal strains isolated from rhizosphere of Arundo donax, Suaeda salsa and Phragmites australis gorwn in coastal saline soil

| PRJNA612589 | ENA

filamentous fungi

Project description:filamentous fungi Targeted loci cultured

| PRJNA422523 | ENA

Potential of bioaugmentation of heavy metal contaminated soils in the Zambian Copperbelt using autochthonous filamentous fungi.

Project description:There is great potential to remediate heavy metal contaminated environments through bioaugmentation with filamentous fungi. However, these fungi have been poorly investigated in most developing countries, such as Zambia. Therefore, the present study aimed at isolating indigenous filamentous fungi from heavy metal contaminated soil and to explore their potential for use in bioaugmentation. The conventional streak plate method was used to isolate fungi from heavy metal-contaminated soil. Filamentous fungal isolates were identified using morphological and molecular techniques. The radial growth diameter technique was used to evaluate heavy metal tolerance of the fungi. The most abundant and highly tolerant fungi, identified as Aspergillus transmontanensis, Cladosporium cladosporioides, and Geotrichum candidum species, were used to bioremediate heavy metal contaminated soil samples with uncontaminated soil sample being employed as a control. A maximum tolerance index (TI) between 0.7 and 11.0 was observed for A. transmontanensis, and G. candidum while C. cladosporioides displayed the TI between 0.2 and 1.2 in the presence of 1,000 ppm of Cu, Co, Fe, Mn, and Zn. The interspecific interaction was analyzed to determine the compatibility among isolates. Our results showed mutual intermingling between the three evaluated fungal species, which confirms their common influence in biomineralization of heavy metals in contaminated soils. Maximum bio-removal capacities after 90 days were 72% for Cu, 99.8% for Co, 60.6% for Fe, 82.2% for Mn, and 100% for both Pb and Zn. This study has demonstrated the potential of highly resistant autochthonous fungal isolates to remediate the heavy metal contamination problem.

| S-EPMC9752026 | biostudies-literature

The Effect of Elevated Curing Temperatures on High Ye'elimite Calcium Sulfoaluminate Cement Mortars.

Project description:This study investigated the material properties and hydration characteristics of calcium sulfoaluminate cement (CSA) based mortars cured under 3 different initial curing temperatures. Two CSA cements with different M-values were selected. Obtained experimental results of mechanical properties, dimensional stability, and heat release were explained by hydration characteristics from X-ray diffraction, thermal gravimetric analysis, porosimetry, and thermodynamic modeling. Decomposition of ettringite decreased compressive strength but re-formation of ettringite after additional curing at 30 °C helped to recover the strength in CSA cement with a high amount of calcium sulfate. CSA cement with a low amount of calcium sulfate which was designed to predominantly have monosulfate as the main hydration product, showed increased 1-day strength after higher temperature curing but this occurred was at the expense of decreased 28-day strength.

| S-EPMC6480238 | biostudies-literature

Effect of Structural Build-Up on Interlayer Bond Strength of 3D Printed Cement Mortars.

Project description:Understanding the relationship between the intrinsic characteristics of materials (such as rheological properties and structural build-up) and printability and controlling intrinsic characteristics of materials through additives to achieve excellent printability is vital in digital concrete additive manufacturing. This paper aims at studying the effects of material's structural build-up on the interlayer bond strength of 3DPC with different time gaps. Structural build-up can indirectly affect the interlayer bond strength by affecting the surface moisture of concrete. Based on the structural build-up of 3DPC, a new parameter, maximum operational time (MOT), is proposed, which can be considered as the limit of time gap to ensure high interlayer bond strength. Slump-retaining polycarboxylate superplasticizer (TS) slightly slows down the physical flocculation rate, but increases the maximum operational time of the cement paste. Nano clay significantly increases the sort-term structural build-up rate and has the function of internal curing and water retaining. Composite with nano-clay and TS can reduce the loss of surface moisture of 3D printed layers, prevent the formation of interface weak layer, and increase the interlayer bond strength between printed layers. This contribution can provide new insight into the design of 3D-printed ink with good extrudability, outstanding buildability, and excellent interlayer bond strength.

| S-EPMC7824854 | biostudies-literature

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