Ontology highlight
ABSTRACT:
SUBMITTER: Gobel C
PROVIDER: S-EPMC7155125 | biostudies-literature | 2020 Mar
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20200203 14
Nanoparticles of the spin-crossover coordination polymer [FeL(bipy)]<sub>n</sub> were synthesized by confined crystallization within the core of polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) diblock copolymer micelles. The 4VP units in the micellar core act as coordination sites for the Fe complex. In the bulk material, the spin-crossover nanoparticles in the core are well isolated from each other allowing thermal treatment without disintegration of their structure. During annealing above ...[more]