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FeCoSe2 Nanoparticles Embedded in g-C3N4: A Highly Active and Stable bifunctional electrocatalyst for overall water splitting.


ABSTRACT: To investigate cost affordable and robust HER and OER catalysts with significant low overpotentials, we have successfully embedded FeCoSe2 spheres on smooth surfaces of graphitic carbon nitride that demonstrated high stability and electrocatalytic activity for H2 production. We systematically analyzed the composition and morphology of FexCo1-xSe2/g-C3N4 and attributed the remarkable electrochemical performance of the catalyst to its unique structure. Fe0.2Co0.8Se2/g-C3N4 showed a superior HER activity, with quite low overpotential value (83?mV at -20 mA cm-2 in 0.5?M H2SO4) and a current density of -3.24, -7.84, -14.80, -30.12?mA?cm-2 at 0?V (vs RHE) in Dulbecco's Phosphate-Buffered Saline (DPBS), artificial sea water (ASW), 0.5?M H2SO4 and 1?M KOH, respectively. To the best of our knowledge, these are the highest reported current densities at this low potential value, showing intrinsic catalytic activity of the synthesized material. Also, the catalyst was found to deliver a high and stable current density of -1000 mA cm-2 at an overpotential of just 317?mV. Moreover, the synthesized catalyst delivered a constant current density of -30 mA cm-2 for 24?h without any noticeable change in potential at -0.2?V. These attributes confer our synthesized catalyst to be used for renewable fuel production and applications.

SUBMITTER: Zulqarnain M 

PROVIDER: S-EPMC7156446 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature

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FeCoSe<sub>2</sub> Nanoparticles Embedded in g-C<sub>3</sub>N<sub>4</sub>: A Highly Active and Stable bifunctional electrocatalyst for overall water splitting.

Zulqarnain Muhammad M   Shah Afzal A   Khan Muhammad Abdullah MA   Jan Iftikhar Faiza F   Nisar Jan J  

Scientific reports 20200414 1


To investigate cost affordable and robust HER and OER catalysts with significant low overpotentials, we have successfully embedded FeCoSe<sub>2</sub> spheres on smooth surfaces of graphitic carbon nitride that demonstrated high stability and electrocatalytic activity for H<sub>2</sub> production. We systematically analyzed the composition and morphology of Fe<sub>x</sub>Co<sub>1-x</sub>Se<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> and attributed the remarkable electrochemical performance of the ca  ...[more]

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