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Sub 1 nm Poly(acrylic acid)-Capped Copper Nanoparticles for the Synthesis of 1,2,3-Triazole Compounds.

ABSTRACT: The stable, water-soluble, and fluorescent sub 1 nm sized poly(acrylic acid)-capped copper nanoparticles (PAACC NPs) were synthesized using a high-intensity ultrasound sonication (30 KHz) method. The reduction of copper NPs from copper(II) salt by mild reducing agent l-ascorbic acid in an aqueous medium was achieved in the presence of poly(acrylic acid). The PAACC NPs were characterized by DRS UV–visible, XPS, PL, FESEM, and HRTEM techniques. The resulting PAACC NPs show orange fluorescence with a peaking center at 560 nm. The PAACC NPs serve as effective catalysts for the synthesis of 1,2,3-triazoles via click reaction in good yields under mild reaction conditions.

SUBMITTER: Abiraman T

PROVIDER: S-EPMC7160833 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature

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