Browse
Submit Data
Databases
API
Help

Dataset Information

26 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Flexible Underwater Oleophobic Cellulose Aerogels for Efficient Oil/Water Separation.

ABSTRACT: Hybrid cellulose/N,N'-methylene bisacrylamide/graphene oxide (GO) aerogels with high flexibility and underwater oleophobicity were fabricated via the NaOH/urea solvent system. The as-prepared aerogels demonstrated low density, high porosity, and good flexibility. Underwater oleophobicity is attributed to the abundant hydrophilic groups in the aerogel skeleton, rough surface, and homogeneous distribution of GO. The samples were shaped into the membrane and filtered for oil/water separation by gravity. The separation efficiency over membrane-shaped CG₁ was 99.8% with a permeate flux of 22,900 L/(m²·h). Moreover, excellent reusability and durability were observed under long-term tests and corrosive conditions.

SUBMITTER: Fu B

PROVIDER: S-EPMC7161048 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Flexible Underwater Oleophobic Cellulose Aerogels for Efficient Oil/Water Separation.

Fu Bo B Yang Qiqi Q Yang Fan F

ACS omega 20200331 14

Hybrid cellulose/<i>N</i>,<i>N</i>'-methylene bisacrylamide/graphene oxide (GO) aerogels with high flexibility and underwater oleophobicity were fabricated via the NaOH/urea solvent system. The as-prepared aerogels demonstrated low density, high porosity, and good flexibility. Underwater oleophobicity is attributed to the abundant hydrophilic groups in the aerogel skeleton, rough surface, and homogeneous distribution of GO. The samples were shaped into the membrane and filtered for oil/water sep ...[more]

PMID: 32309728

Similar Datasets

Green, Biodegradable, Underwater Superoleophobic Wood Sheet for Efficient Oil/Water Separation.

Project description:Superwettable (by water or oil) materials have been used in oil/water separation to cope with the growing oily industrial sewage discharge and oil spill accidents. The artificial superwetting materials for oil/water separation that have been previously reported are expensive, and using them usually causes secondary pollution, so practical, large-scale uses of those materials are limited. Here, we find that wood sheet shows underwater superoleophobicity and low oil adhesion in water, resulting from its strong capacity of absorbing water. A through-microhole array was created on the wood sheet surface by a simple mechanical drilling process. The prewetted porous sheet had great ability to separate the mixtures of water and oil with high separation efficiency. Wood is a low cost, green, and natural eco-friendly material; therefore, we believe that such a simple, low-cost, efficient, and green route of large-scale oil/water separation has great potential to practically solve the pollution problems caused by oil spill and oily industrial wastewater.

| S-EPMC6641444 | biostudies-literature

Biomass Chitosan-Based Tubular/Sheet Superhydrophobic Aerogels Enable Efficient Oil/Water Separation.

Project description:Water pollution, which is caused by leakage of oily substances, has been recognized as one of the most serious global environmental pollutions endangering the ecosystem. High-quality porous materials with superwettability, which are typically constructed in the form of aerogels, hold huge potential in the field of adsorption and removal of oily substances form water. Herein, we developed a facile strategy to fabricate a novel biomass absorbent with a layered tubular/sheet structure for efficient oil/water separation. The aerogels were fabricated by assembling hollow poplar catkin fiber into chitosan sheets using a directional freeze-drying method. The obtained aerogels were further wrapped with -CH3-ended siloxane structures using CH3SiCl3. This superhydrophobic aerogel (CA ≈ 154 ± 0.4°) could rapidly trap and remove oils from water with a large sorption range of 33.06-73.22 g/g. The aerogel facilitated stable oil recovery (90.07-92.34%) by squeezing after 10 sorption-desorption cycles because of its mechanical robustness (91.76% strain remaining after 50 compress-release cycles). The novel design, low cost, and sustainability of the aerogel provide an efficient and environmentally friendly solution for handling oil spills.

| S-EPMC10137560 | biostudies-literature

Highly reusable and superhydrophobic spongy graphene aerogels for efficient oil/water separation.

Project description:Graphene aerogels (GAs) are three-dimensional (3D) graphene sponges with unique wettability and have demonstrated the potential for reducing contamination from oil spills and chemical accidents. Herein, we report new polyurethane (PU) sponge-reinforced GAs with low surface energy, high sorption capacity and excellent recyclability for use as efficient oil sorbents. Spongy graphene aerogels (SGAs) with a hierarchical porous morphology were produced by simply freeze-casting reduced graphene oxide (rGO) to form compacted macroscale sponges. This novel micro-structure benefits from the advantages of embedded graphene and presents reversible large-strain deformation (90%), high compressive strength (63 kpa) and viscoelastic stability. These superior properties, in addition to super-hydrophobicity, endow the aerogels with excellent recyclability without deteriorating the oil absorption performance. Furthermore, SGA has selective and high-volume absorbability (>100%) and can efficiently separate oil from water under continuous pumping action. The excellent absorption performance and robust mechanical properties make this graphene material promising for the large-scale recovery of spilled oil.

| S-EPMC5540914 | biostudies-literature

Clay-Coated Meshes with Superhydrophilicity and Underwater Superoleophobicity for Highly Efficient Oil/Water Separation.

Project description:A novel clay-coated mesh was fabricated via a simple brush-coating method without the use of special equipment, chemical reagents, and complex chemical reactions and operation processes. Possessing superhydrophilicity and underwater superoleophobicity, the clay-coated mesh can be used for efficiently separating various light oil/water mixtures. The clay-coated mesh also exhibits excellent reusability, maintaining a high separation efficiency of 99.4% after 30 repeated separations of the kerosene/water mixture.

| S-EPMC10304548 | biostudies-literature

Flexible Superhydrophobic and Superoleophilic MoS2 Sponge for Highly Efficient Oil-Water Separation.

Project description:Removal of oils and organic solvents from water is an important global challenge for energy conservation and environmental protection. Advanced sorbent materials with excellent sorption capacity need to be developed. Here we report on a superhydrophobic and superoleophilic MoS2 nanosheet sponge (SMS) for highly efficient separation and absorption of oils or organic solvents from water. This novel sponge exhibits excellent absorption performance through a combination of superhydrophobicity, high porosity, robust stability in harsh conditions (including flame retardance and inertness to corrosive and different temperature environments) and excellent mechanical properties. The dip-coating strategy proposed for the fabrication of the SMS, which does not require a complicated process or sophisticated equipment, is very straightforward and easy to scale up. This finding shows promise for water remediation and oil recovery.

| S-EPMC4897779 | biostudies-literature

Reversible Wettability between Underwater Superoleophobicity and Superhydrophobicity of Stainless Steel Mesh for Efficient Oil-Water Separation.

Project description:Design and fabrication of smart materials with reversible wettability for oil-water separation have attracted worldwide attention due to the increasingly serious water pollution problem. In this study, a rough oxide coating with micro/nanoscale structures is developed on the 304 stainless steel mesh (SSM) by laser ablation. The smart surface with ethanol immersion and natural drying treatments shows the wetting conversion between underwater superoleophobicity and superhydrophobicity. Based on the wettability transition behavior, both light and heavy oil-water mixtures can be separated with the high separation efficiency. Moreover, after being exposed to various corrosive solutions and high temperatures, the smart surface still shows prominent environmental stability. Switchable surface with excellent properties should be an optimal choice to solve the environmental conditions that need to be addressed urgently.

| S-EPMC7807473 | biostudies-literature

A self-cleaning underwater superoleophobic mesh for oil-water separation.

Project description:Oil-water separation has recently become a global challenging task because of the frequent occurrence of oil spill accidents due to the offshore oil production and transportation, and there is an increasing demand for the development of effective and inexpensive approaches for the cleaning-up of the oily pollution in water system. In this study, a self-cleaning underwater superoleophobic mesh that can be used for oil-water separation is prepared by the layer-by-layer (LbL) assembly of sodium silicate and TiO2 nanoparticles on the stainless steel mesh. The integration of the self-cleaning property into the all-inorganic separation mesh by using TiO2 enables the convenient removal of the contaminants by ultraviolet (UV) illumination, and allows for the facile recovery of the separation ability of the contaminated mesh, making it promising for practial oil-water separation applications.

| S-EPMC3728594 | biostudies-literature

Facile Fabrication of Superhydrophobic Cross-Linked Nanocellulose Aerogels for Oil-Water Separation.

Project description:A facile and environmental-friendly approach was developed for the preparation of the cross-linked nanocellulose aerogel through the freeze-drying process and subsequent esterification. The as-prepared aerogel had a three-dimensional cellular microstructure with ultra-low density of 6.05 mg·cm-3 and high porosity (99.61%). After modifying by chemical vapor deposition (CVD) with hexadecyltrimethoxysilane (HTMS), the nanocellulose aerogel displayed stable super-hydrophobicity and super-oleophilicity with water contact angle of 151°, and had excellent adsorption performance for various oil and organic solvents with the adsorption capacity of 77~226 g/g. Even after 30 cycles, the adsorption capacity of the nanocellulose aerogel for chloroform was as high as 170 g/g, indicating its outstanding reusability. Therefore, the superhydrophobic cross-linked nanocellulose aerogel is a promising oil adsorbent for wastewater treatment.

| S-EPMC7921982 | biostudies-literature

Underwater superoleophobic polyurethane-coated mesh with excellent stability for oil/water separation.

Project description:Oil/water separation has been a challenge in chemical engineering for various applications. There are numbers of studies on using coated metal meshes as a filter for oil/water separation. However, water resistance, chemical (such as: acid, base, and fouling) resistance and heat resistance for coating materials need further exploration, especially in terms of the durability of the coating materials. In this study, we synthesized a new coating material, hydrophilic polycarbonate polyurethane (HPCPU). We used HPCPU to chemically modify a steel mesh, and the mesh exhibits superhydrophilic and underwater superoleophobic properties. The HPCPU coated mesh shows excellent capacity for oil/water separation with a separation efficiency higher than 99.99% even after 40 cycles of separation. The coating material also exhibits excellent properties of water resistance, heat resistance, and chemical resistance. Moreover, the HPCPU-coated mesh exhibits a strong durability. For example, the separation efficiency for various oil/water mixtures remains higher than 99.7% after the HPCPU-coated mesh has been soaked in water for 30 days, hot water for 5 days, oils for 5 days, 0.5 M HCl solution, 0.5 M NaOH solution and 0.5 M NaCl solution for 24 hours.

| S-EPMC9090853 | biostudies-literature

Mechanically Robust and Flexible GO/PI Hybrid Aerogels as Highly Efficient Oil Absorbents

Project description:Herein, mechanically robust and flexible graphene oxide/polyimide (GO/PI) hybrid aerogels (GIAs) were fabricated by a facile method, in which the mixed suspensions of the water-soluble polyimide precursor and graphene oxide (GO) sheets were freeze-dried, which was followed by a routine thermal imidation process. The porous GIAs obtained not only exhibit excellent elasticity and extremely low density values (from 33.3 to 38.9 mg.cm−3), but they also possess a superior compressive strength (121.7 KPa). The GIAs could support a weight of up to 31,250 times of its own weight, and such a weight-carrying capacity is much higher than that of other typical carbon-based aerogels. Having such a porous structure, and high strength and toughness properties make GIAs ideal candidates for oil spill cleanup materials. The oil/organic solvents’ absorption capacity ranges from 14.6 to 85, which is higher than that of most other aerogels (sponges). With their broad temperature tolerance and acidic stability, the unique multifunctional GIAs are expected to further extend their application range into extreme environments.

| S-EPMC9696896 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data