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Per-Alkoxy-pillar[5]arenes as Electron Donors: Electrochemical Properties of Dimethoxy-Pillar[5]arene and Its Corresponding Rotaxane.


ABSTRACT: 1,4-dimethoxypillar[5]arene undergoes reversible multielectron oxidations forming stable radical cations, a property retained when incorporated in [2]rotaxanes, suggesting that pillar[5]arenes can be employed as viable, yet unreported, electron donors.

SUBMITTER: Pearce N 

PROVIDER: S-EPMC7180461 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature

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<i>per</i>-Alkoxy-pillar[5]arenes as Electron Donors: Electrochemical Properties of Dimethoxy-Pillar[5]arene and Its Corresponding Rotaxane.

Pearce Nicholas N   Davies E Stephen ES   Champness Neil R NR  

Molecules (Basel, Switzerland) 20200402 7


1,4-dimethoxypillar[5]arene undergoes reversible multielectron oxidations forming stable radical cations, a property retained when incorporated in [2]rotaxanes, suggesting that pillar[5]arenes can be employed as viable, yet unreported, electron donors. ...[more]

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