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per-Hydroxylated Prism[n]arenes: Supramolecularly Assisted Demethylation of Methoxy-Prism[5]arene.

ABSTRACT: Methoxy-prism[5]arene PrS[5]^Me is demethylated by a supramolecularly assisted reaction. In the presence of a tetramethylammonium cation, PrS[5]^Me is demethylated by BBr₃ in high yield, while in its absence a 55/40 mixture of PrS[5]^OH/PrS[6]^OH is formed. The dealkylation of prismarenes, such as PrS[6]^R (R = Et, nPr) and c-PrS[5]^Me, can be easily obtained in high yields in the presence of BBr₃.

SUBMITTER: Del Regno R

PROVIDER: S-EPMC8576831 | biostudies-literature |

REPOSITORIES: biostudies-literature

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