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Trace Ethylene Sensing via Wacker Oxidation.


ABSTRACT: Ethylene is a dynamic plant hormone, and its temporal monitoring can be used to glean insight into plant health and status. However, the real-time distributed detection of ethylene at trace levels under ambient conditions remains a challenge. We report a single-walled carbon nanotube-based chemiresistor catalyst combination that can detect ppb levels of ethylene in air. Cycling between Pd(II) and Pd(0) via Wacker oxidation with a nitrite cocatalyst imparts response discrimination driven by the chemoselectivity of the chemical transformation. Sensitivity is controlled by a combination of the chemical reaction efficiency and the n-doping strength of the Pd(0) species generated in situ. The covalent functionalization of the carbon nanotube sidewall with pyridyl ligands drastically improves the device sensitivity via enhanced n-doping. The utility of this ethylene sensor is demonstrated in the monitoring of senescence in red carnations and purple lisianthus flowers.

SUBMITTER: Fong D 

PROVIDER: S-EPMC7181324 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature

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Trace Ethylene Sensing via Wacker Oxidation.

Fong Darryl D   Luo Shao-Xiong SX   Andre Rafaela S RS   Swager Timothy M TM  

ACS central science 20200318 4


Ethylene is a dynamic plant hormone, and its temporal monitoring can be used to glean insight into plant health and status. However, the real-time distributed detection of ethylene at trace levels under ambient conditions remains a challenge. We report a single-walled carbon nanotube-based chemiresistor catalyst combination that can detect ppb levels of ethylene in air. Cycling between Pd(II) and Pd(0) via Wacker oxidation with a nitrite cocatalyst imparts response discrimination driven by the c  ...[more]

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