Enhanced Electrical Conductivity and Seebeck Coefficient in PEDOT:PSS via a Two-Step Ionic liquid and NaBH₄ Treatment for Organic Thermoelectrics.

ABSTRACT: A two-step approach of improving the thermoelectric properties of Poly(3,4-ethylenedioxythiophene)poly(4-styrenesulfonate) (PEDOT:PSS) via the addition of the ionic liquid, 1-Ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMIM:TFSI) and subsequent reduction with NaBH₄ is presented. The addition of 2.5 v/v% of EMIM:TFSI to PEDOT:PSS increases the electrical conductivity from 3 S·cm^-1 to 1439 S·cm^-1 at 40 °C. An additional post treatment using the reducing agent, NaBH₄, increases the Seebeck coefficient of the film from 11 µV·K^-1 to 30 µV·K^-1 at 40 °C. The combined treatment gives an overall improvement in power factor increase from 0.04 µW·m^-1·K^-2 to 33 µW·m^-1·K^-2 belo

SUBMITTER: Atoyo J 

PROVIDER: S-EPMC7182861 | biostudies-literature | 2020 Mar

REPOSITORIES: biostudies-literature