Ontology highlight
ABSTRACT:
SUBMITTER: Bagi P
PROVIDER: S-EPMC7189000 | biostudies-literature | 2020
REPOSITORIES: biostudies-literature
Bagi Péter P Herbay Réka R Péczka Nikolett N Mucsi Zoltán Z Timári István I Keglevich And György AG
Beilstein journal of organic chemistry 20200422
A series of 1-substituted-3-methyl-2-phospholene oxides was prepared from the corresponding 3-phospholene oxides by double bond rearrangement. The 2-phospholene oxides could be obtained by heating the 3-phospholene oxides in methanesulfonic acid, or via the formation of cyclic chlorophosphonium salts. Whereas mixtures of the 2- and 3-phospholene oxides formed, when the isomerization of 3-phospholene oxides was attempted under thermal conditions, or in the presence of a base. The mechanisms of th ...[more]