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Crystal structure and Hirshfeld surface analysis of 2-phenyl-1H-phenanthro[9,10-d]imidazol-3-ium benzoate.

ABSTRACT: In the title compound, C21H15N2 +·C7H5O2 -, 2-phenyl-1H-phenanthro[9,10-d]imidazole and benzoic acid form an ion pair complex. The system is consolidated by hydrogen bonds along with ?-? inter-actions and N-H?? inter-actions between the constituent units. For a better understanding of the crystal structure and inter-molecular inter-actions, a Hirshfeld surface analysis was performed.

SUBMITTER: Ahmed R

PROVIDER: S-EPMC7199257 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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Crystal structure and Hirshfeld surface analysis of 2-phenyl-1H-phenanthro[9,10-d]imidazol-3-ium benzoate.

Ahmed Ruby R Doğan Onur Erman OE Ali Farman F Ahmad Musheer M Ahmed Adeeba A Dege Necmi N Golenia Irina A IA

Acta crystallographica. Section E, Crystallographic communications 20200424 Pt 5

In the title compound, C21H15N2 +·C7H5O2 -, 2-phenyl-1H-phenanthro[9,10-d]imidazole and benzoic acid form an ion pair complex. The system is consolidated by hydrogen bonds along with π-π inter-actions and N-H⋯π inter-actions between the constituent units. For a better understanding of the crystal structure and inter-molecular inter-actions, a Hirshfeld surface analysis was performed. ...[more]

PMID: 32431940

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