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Feasibility Study on the Use of Recycled Polymers for Malathion Adsorption: Isotherms and Kinetic Modeling.

ABSTRACT: In this study, the use of Polyvinylchloride (PVC) and High Density Polystyrene (HDPS) was demonstrated as an alternative for the adsorption of Malathion. Adsorption kinetics and isotherms were used to compare three different adsorbent materials: PVC, HDPS, and activated carbon. The adsorption capacity of PVC was three times higher than activated carbon, and a theoretical value of 96.15 mg of Malathion could be adsorbed when using only 1 g of PVC. A pseudo first-order rate constant of 1.98 (1/h) was achieved according to Lagergren kinetic model. The adsorption rate and capacity values obtained in the present study are very promising since with very little adsorbent material it is possible to obtain high removal efficiencies. Phosphorous and sulfur elements were identified through Energy Dispersive X-ray (EDX) analysis and evidenced the malathion adsorption on PVC. The characteristic spectrum of malathion was identified by the Fourier Transform Infrared (FTIR) Spectroscopy analysis. The Thermogravimetric and Differential Thermal Analysis (TG/DTA) suggested that the adsorption of malathion on the surface of the polymers was mainly determined by hydrogen bonds.

SUBMITTER: Hermosillo-Nevarez JJ

PROVIDER: S-EPMC7215715 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature

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Feasibility Study on the Use of Recycled Polymers for Malathion Adsorption: Isotherms and Kinetic Modeling.

Hermosillo-Nevárez Jhonatan J JJ Bustos-Terrones Victoria V Bustos-Terrones Yaneth A YA Uriarte-Aceves Perla Marysol PM Rangel-Peraza Jesus Gabriel JG

Materials (Basel, Switzerland) 20200412 8

In this study, the use of Polyvinylchloride (PVC) and High Density Polystyrene (HDPS) was demonstrated as an alternative for the adsorption of Malathion. Adsorption kinetics and isotherms were used to compare three different adsorbent materials: PVC, HDPS, and activated carbon. The adsorption capacity of PVC was three times higher than activated carbon, and a theoretical value of 96.15 mg of Malathion could be adsorbed when using only 1 g of PVC. A pseudo first-order rate constant of 1.98 (1/h) ...[more]

PMID: 32290629

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Project description:A scaling theory is developed for selective adsorption of polymers induced by the strong binding between specific monomers and complementary surface adsorption sites. By "selective" we mean specific attraction between a subset of all monomers, called "sticky", and a subset of surface sites, called "adsorption sites". We demonstrate that, in addition to the expected dependence on the polymer volume fraction ?bulk in the bulk solution, selective adsorption strongly depends on the ratio between two characteristic length scales, the root-mean-square distance l between neighboring sticky monomers along the polymer, and the average distance d between neighboring surface adsorption sites. The role of the ratio l/d arises from the fact that a polymer needs to deform to enable the spatial commensurability between its sticky monomers and the surface adsorption sites for selective adsorption. We study strong selective adsorption of both telechelic polymers with two end monomers being sticky and multisticker polymers with many sticky monomers between sticky ends. For telechelic polymers, we identify four adsorption regimes at l/d < 1 that are characterized by the fraction of occupied adsorption sites and whether the dominant conformation of adsorbed chains is a single-end-adsorbed "mushroom" or double-end-adsorbed loop. For l/d > 1, we expect that the adsorption layer at exponentially low ?bulk consists of separated unstretched loops, while as ?bulk increases the layer crosses over to a brush of extended loops with a second layer of weakly overlapping tails. For multisticker chains, in the limit of exponentially low ?bulk, adsorbed polymers are well separated from each other. As l/d increases, the conformation of an individual polymer changes from a single-end-adsorbed "mushroom" to a random walk of loops. For high ?bulk, adsorbed polymers at small l/d are mushrooms that cover all the adsorption sites. At sufficiently large l/d, adsorbed multisticker polymers strongly overlap. We anticipate the formation of a self-similar carpet and with increasing l/d a two-layer structure with a brush of loops covered by a self-similar carpet. As l/d exceeds the threshold determined by the adsorption energy, the brush of loops under the carpet reaches a saturated state, resulting in a l/d-independent brush-under-carpet structure, which can also be applied to describe adsorbed multisticker polymers in nonselective adsorption where a sticker can strongly bind to any place on the adsorption surface. We examine the adsorbed amount ? of multisticker polymers in different regimes for selective adsorption. If the adsorbed multisticker polymers are nonoverlapping mushrooms, the adsorbed amount ? increases linearly with the surface density of adsorption sites ? ? 1/d(2). In the self-similar carpet regime, ? increases sublinearly as ?(0.15) in a good solvent, while only logarithmically in a theta solvent. Formation of a brush layer under the carpet contributes an additional adsorbed amount. This additional amount increases linearly with ? and eventually dominates the overall adsorbed amount ? before saturating at a plateau value controlled by the adsorption energy.

Project description:Unlabelled(18)F-fluoromisonidazole dynamic PET (dPET) is used to identify tumor hypoxia noninvasively. Its routine clinical implementation, however, has been hampered by the long acquisition times required. We investigated the feasibility of kinetic modeling using shortened acquisition times in (18)F-fluoromisonidazole dPET, with the goal of expediting the clinical implementation of (18)F-fluoromisonidazole dPET protocols.MethodsSix patients with squamous cell carcinoma of the head and neck and 10 HT29 colorectal carcinoma-bearing nude rats were studied. In addition to an (18)F-FDG PET scan, each patient underwent a 45-min (18)F-fluoromisonidazole dPET scan, followed by 10-min acquisitions at 96 ± 4 and 163 ± 17 min after injection. Ninety-minute (18)F-fluoromisonidazole dPET scans were acquired in animals. Intratumor voxels were classified into 4 clusters based on their kinetic behavior using k-means clustering. Kinetic modeling was performed using the foregoing full datasets (FD) and repeated for each of 2 shortened datasets corresponding to the first approximately 100 min (SD1; patients only) or the first 45 min (SD2) of dPET data. The kinetic rate constants (KRCs) as calculated with a 2-compartment model for both SD1 and SD2 were compared with those derived from FD by correlation (Pearson), regression (Passing-Bablok), deviation (Bland-Altman), and classification (area-under-the-receiver-operating characteristic curve) analyses. Simulations were performed to assess uncertainties due to statistical noise.ResultsStrong correlation (r ≥ 0.75, P < 0.001) existed between all KRCs deduced from both SD1 and SD2, and from FD. Significant differences between KRCs were found only for FD-SD2 correlations in patient studies. K1 and k3 were reproducible to within approximately 6% and approximately 30% (FD-SD1; patients) and approximately 4% and approximately 75% (FD-SD2; animals). Area-under-the-receiver-operating characteristic curve values for classification of patient clusters as hypoxic, using a tumor-to-blood ratio greater than 1.2, were 0.91 (SD1) and 0.86 (SD2). The percentage SD in estimating K1 and k3 from 45-min shortened datasets due to noise was less than 1% and between 2% and 12%, respectively.ConclusionUsing single-session 45-min shortened (18)F-fluoromisonidazole dPET datasets appears to be adequate for the identification of intratumor regions of hypoxia. However, k3 was significantly overestimated in the clinical cohort. Further studies are necessary to evaluate the clinical significance of differences between the results as calculated from full and shortened datasets.

Dataset Information

Feasibility Study on the Use of Recycled Polymers for Malathion Adsorption: Isotherms and Kinetic Modeling.

Publications

Feasibility Study on the Use of Recycled Polymers for Malathion Adsorption: Isotherms and Kinetic Modeling.

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