Ontology highlight
ABSTRACT:
SUBMITTER: Qin L
PROVIDER: S-EPMC7216293 | biostudies-literature | 2019 Oct
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20191015 43
The direct conversion of C-H bonds into new C-C bonds represents a powerful approach to generate complex molecules from simple starting materials. However, a general and controllable method for the sequential conversion of a methyl group into a fully substituted carbon center remains a challenge. We report a new method for the selective and sequential replacement of three C-H bonds at the allylic position of propylene and other simple terminal alkenes with different carbon groups derived from Gr ...[more]