Dataset Information

Enhanced Solar Light Photocatalytic Activity of Ag Doped TiO₂-Ag₃PO₄ Composites.

ABSTRACT: Composites comprised of Ag₃PO₄ and bare TiO₂ (TiO₂@Ag₃PO₄) or silver doped TiO₂ (Ag@TiO₂-Ag₃PO₄) have been synthesized by coupling sol-gel and precipitation methods. For the sake of comparison, also the bare components have been similarly prepared. All the samples have been characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy (DRS), scanning electron microscopy (SEM), Fourier transformed infrared spectroscopy (FTIR), photoelectrochemical measurements, and specific surface area (SSA) analysis. The optoelectronic and structural features of the samples have been related to their photocatalytic activity for the degradation of 4-nitrophenol under solar and UV light irradiation. Coupling Ag₃PO₄ with silver doped TiO₂ mitigates photocorrosion of the Ag₃PO₄ counterpart, and remarkably improves the photocatalytic activity under solar light irradiation with respect to the components, to the TiO₂-Ag₃PO₄ sample, and to the benchmark TiO₂ Evonik P25. These features open the route to future applications of this material in the field of environmental remediation.

SUBMITTER: Hamrouni A

PROVIDER: S-EPMC7221970 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature

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Publications

Enhanced Solar Light Photocatalytic Activity of Ag Doped TiO2-Ag3PO4 Composites.

Hamrouni Abdessalem A Azzouzi Hanen H Rayes Ali A Palmisano Leonardo L Ceccato Riccardo R Parrino Francesco F

Nanomaterials (Basel, Switzerland) 20200421 4

Composites comprised of Ag3PO4 and bare TiO2 (TiO2@Ag3PO4) or silver doped TiO2 (Ag@TiO2-Ag3PO4) have been synthesized by coupling sol-gel and precipitation methods. For the sake of comparison, also the bare components have been similarly prepared. All the samples have been characterized by X-ray diffraction (XRD), UV-vis diffuse reflectance spectroscopy (DRS), scanning electron microsco ...[more]

PMID: 32326155

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Project description:Background purposePhotocatalytic water splitting for hydrogen evolution is a potential way to solve many energy and environmental issues. Developing visible-light-active photocatalysts to efficiently utilize sunlight and finding proper ways to improve photocatalytic activity for H2 evolution have always been hot topics for research. This study attempts to expand the use of sunlight and to enhance the photocatalytic activity of TiO2 by N doping and Au loading.MethodsAu/N-doped TiO2 photocatalysts were synthesized and successfully used for photocatalytic water splitting for H2 evolution under irradiation of UV and UV-vis light, respectively. The samples were characterized using X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (DRS), photoluminescence spectroscopy (PL), and photoelectrochemical characterizations.ResultsDRS displayed an extension of light absorption into the visible region by doping of N and depositing with Au, respectively. PL analysis indicated electron-hole recombination due to N doping and an efficient inhibition of electron-hole recombination due to the loaded Au particles. Under the irradiation of UV light, the photocatalytic hydrogen production rate of the as-synthesized samples followed the order Au/TiO2 > Au/N-doped TiO2 > TiO2 > N-doped TiO2. While under irradiation of UV-vis light, the N-TiO2 and Au/N-TiO2 samples show higher H2 evolution than their corresponding nitrogen-free samples (TiO2 and Au/TiO2). This inconsistent result could be attributed to the doping of N and the surface plasmonic resonance (SPR) effect of Au particles extending the visible light absorption. The photoelectrochemical characterizations further indicated the enhancement of the visible light response of Au/N-doped TiO2.ConclusionComparative studies have shown that a combination of nitrogen doping and Au loading enhanced the visible light response of TiO2 and increased the utilization of solar energy, greatly boosting the photocatalytic activity for hydrogen production under UV-vis light.

Dataset Information

Enhanced Solar Light Photocatalytic Activity of Ag Doped TiO₂-Ag₃PO₄ Composites.

Publications

Enhanced Solar Light Photocatalytic Activity of Ag Doped TiO<sub>2</sub>-Ag<sub>3</sub>PO<sub>4</sub> Composites.

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