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Polyaspartic Acid-Derived Micro-/Mesoporous Carbon for Ultrahigh H2 and CH4 Adsorption.


ABSTRACT: A poly(amino acid)-based approach for scalable synthesis of micro-/mesoporous carbon (PC) with high specific surface area and narrow distribution of micro- and mesopores is presented. Using cross-linked poly aspartic acid as a precursor, PC was obtained by in situ one-step carbonization without the activating agent. The resulting PC had an ultrahigh adsorption capacity for H2 (4.43 wt %) and CH4 (4.49 mmol g-1). This novel method could significantly decrease the wastewater hazards caused by washout of the considerable amount of the activating agent. The PC showed promising application in gas adsorption and storage.

SUBMITTER: Zhao J 

PROVIDER: S-EPMC7240811 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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Polyaspartic Acid-Derived Micro-/Mesoporous Carbon for Ultrahigh H<sub>2</sub> and CH<sub>4</sub> Adsorption.

Zhao Jianbo J   Wei Jun J   Cai Di D   Cao Hui H   Tan Tianwei T  

ACS omega 20200511 19


A poly(amino acid)-based approach for scalable synthesis of micro-/mesoporous carbon (PC) with high specific surface area and narrow distribution of micro- and mesopores is presented. Using cross-linked poly aspartic acid as a precursor, PC was obtained by in situ one-step carbonization without the activating agent. The resulting PC had an ultrahigh adsorption capacity for H<sub>2</sub> (4.43 wt %) and CH<sub>4</sub> (4.49 mmol g<sup>-1</sup>). This novel method could significantly decrease the  ...[more]

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