Synthesis and crystal structure of two manganese-based 12-metallacrown-4 complexes: Na₂(3-chloro-benzoate)₂[12-MC_{Mn(III)N(shi)}-4](DMF)₆ and MnNa(3-chloro-benzoate)₃[12-MC_{Mn(III)N(shi)}-4](DMF)(H₂O)₄·4DMF·0.72H₂O.

ABSTRACT: Similar synthetic schemes yield two different metallacrown (MC) complexes: bis-(μ-3-chloro-benzoato)hexa-kis-(di-methyl-formamide)-tetra-kis-(μ₄-N,2-dioxido-benzene-1-carboximidato)tetra-manganese(III)disodium(I), [Mn₄Na₂(C₇H₄ClO₂)₂(C₇H₄NO₃)₄(C₃H₇NO)₆] or Na₂(3-chloro-benzoate)₂[12-MC_{Mn(III)N(shi)}-4](DMF)₆, 1, and tetra-μ-aqua-tris-(μ-3-chloro-benzoato)(di-methyl-formamide)-tetra-kis-(μ₄-N,2-dioxido-benzene-1-carboximidato)penta-manganese(III)sodi-um(I) di-methyl-formamide tetra-solvate 0.72-hydrate, [Mn₅Na(C₇H₄ClO₂)

SUBMITTER: Zaleski CM 

PROVIDER: S-EPMC7274016 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature