Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

One-step sorting of single-walled carbon nanotubes using aqueous two-phase extraction in the presence of basic salts.

ABSTRACT: We demonstrate a simple one-step approach to separate (6,5) CNTs from raw material by using the aqueous two-phase extraction method. To reach this goal, stable and inexpensive K₂CO₃, Na₂CO₃, Li₂CO_3, and K₃PO₄ basic salts are used as modulators of the differentiation process. Under the appropriate parameters, near monochiral fractions become available for straightforward harvesting. In parallel, we show that the isolation process is strongly affected not only by pH but by the inherent nature of the introduced chemical species as well. The results of our study also reveal that the commonly used ingredients of the biphasic system make a strong contribution to the course of the separation by having far from neutral pH values themselves.

SUBMITTER: Podlesny B

PROVIDER: S-EPMC7280227 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

One-step sorting of single-walled carbon nanotubes using aqueous two-phase extraction in the presence of basic salts.

Podlesny Blazej B Shiraki Tomohiro T Janas Dawid D

Scientific reports 20200608 1

We demonstrate a simple one-step approach to separate (6,5) CNTs from raw material by using the aqueous two-phase extraction method. To reach this goal, stable and inexpensive K2CO3, Na2CO3, Li2CO3, and K3PO4 basic salts are used as modulators of the differentiation process. Under the appropriate parameters, near monochiral fractions become available for straightforward harvesting. In parallel, we show that t ...[more]

PMID: 32513999

Similar Datasets

Single-step extraction of small-diameter single-walled carbon nanotubes in the presence of riboflavin.

Project description:We propose a novel approach to disperse and extract small-diameter single-walled carbon nanotubes (SWCNTs) using an aqueous solution of riboflavin and Sephacryl gel. The extraction of small-diameter semiconducting SWCNTs was observed, regardless of the initial diameter distribution of the SWCNTs. Dispersion of SWCNTs occurs due to the adsorption of π-conjugated isoalloxazine moieties on the surface of small-diameter nanotubes and interactions between hydroxy groups of ribityl chains with water. During the SWCNT extraction, specific adsorption of riboflavin to SWCNTs leads to the minimization of interactions between the SWCNTs and gel media. Our experimental findings are supported by ab initio calculations demonstrating the impact of the riboflavin wrapping pattern around the SWCNTs on their interaction with the allyl dextran gel.

| S-EPMC9795860 | biostudies-literature

Self-Sorting of 10-µm-Long Single-Walled Carbon Nanotubes in Aqueous Solution.

Project description:Single-walled carbon nanotubes (SWCNTs) are a class of 1D nanomaterials that exhibit extraordinary electrical and optical properties. However, many of their fundamental studies and practical applications are stymied by sample polydispersity. SWCNTs are synthesized in bulk with broad structural (chirality) and geometrical (length and diameter) distributions; problematically, all known post-synthetic sorting methods rely on ultrasonication, which cuts SWCNTs into short segments (typically <1 µm). It is demonstrated that ultralong (>10 µm) SWCNTs can be efficiently separated from shorter ones through a solution-phase "self-sorting". It is shown that thin-film transistors fabricated from long semiconducting SWCNTs exhibit a carrier mobility as high as ?90 cm2 V-1 s-1 , which is ?10 times higher than those which use shorter counterparts and well exceeds other known materials such as organic semiconducting polymers (<1 cm2 V-1 s-1 ), amorphous silicon (?1 cm2 V-1 s-1 ), and nanocrystalline silicon (?50 cm2 V-1 s-1 ). Mechanistic studies suggest that this self-sorting is driven by the length-dependent solution phase behavior of rigid rods. This length sorting technique shows a path to attain long-sought ultralong, electronically pure carbon nanotube materials through scalable solution processing.

| S-EPMC6692235 | biostudies-literature

Sorting centimetre-long single-walled carbon nanotubes.

Project description:While several approaches have been developed for sorting metallic (m) or semiconducting (s) single-walled carbon nanotubes (SWCNTs), the length of SWCNTs is limited within a micrometer, which restricts excellent electrical performances of SWCNTs for macro-scale applications. Here, we demonstrate a simple sorting method of centimetre-long aligned m- and s-SWCNTs. Ni particles were selectively and uniformly coated along the 1-cm-long m-SWCNTs by applying positive gate bias during electrochemical deposition with continuous electrolyte injection. To sort s-SWCNTs, the Ni coating was oxidized to form insulator outer for blocking of current flow through inner m-SWCNTs. Sorting of m-SWCNTs were demonstrated by selective etching of s-SWCNTs via oxygen plasma, while the protected m-SWCNTs by Ni coating remained intact. The series of source-drain pairs were patterned along the 1-cm-long sorted SWCNTs, which confirmed high on/off ratio of 10(4)-10(8) for s-SWCNTs and nearly 1 for m-SWCNTs.

| S-EPMC4967858 | biostudies-literature

A one-step route to solubilised, purified or functionalised single-walled carbon nanotubes.

Project description:Reductive dissolution is a promising processing route for single walled carbon nanotubes (SWCNTs) that avoids the damage caused by ultrasonication and aggressive oxidation whilst simultaneously allowing access to a wealth of SWCNT functionalisation reactions. Here, reductive dissolution has been simplified to a single one-pot reaction through the use of sodium naphthalide in dimethylacetamide allowing direct synthesis of SWCNT Na+ solutions. Gram quantities of SWCNTs can be dissolved at concentrations over 2 mg mL-1. These reduced SWCNT solutions can easily be functionalised through the addition of alkyl halides; reducing steric bulk of the grafting moiety and increasing polarisability of the leaving group increases the extent of functionalisation. An optimised absolute sodium concentration of 25 mM is shown to be more important than carbon to metal ratio in determining the maximum degree of functionalisation. This novel dissolution system can be modified for use as a non-destructive purification route for raw SWCNT powder by adjusting the degree of charging to dissolve carbonaceous impurities, catalyst particles and defective material, before processing the remaining SWCNTs.

| S-EPMC4786951 | biostudies-literature

Variations in bile salt surfactant structure allow tuning of the sorting of single-wall carbon nanotubes by aqueous two-phase extraction.

Project description:Being some of the most efficient agents to individually solubilize single-wall carbon nanotubes (SWCNTs), bile salt surfactants (BSS) represent the foundation for the surfactant-based structure sorting and spectroscopic characterization of SWCNTs. In this work, we investigate three BSS in their ability to separate different SWCNT chiral structures by aqueous two-phase extraction (ATPE): sodium deoxycholate (DOC), sodium cholate (SC) and sodium chenodeoxycholate (CDOC). The small difference in their chemical structure (just one hydroxyl group) leads to significant differences in their stacking behavior on SWCNT walls with different diameter and chiral structure that, in turn, has direct consequences for the chiral sorting of SWCNTs using these BSS. By performing several series of systematic ATPE experiments, we reveal that, in general, the stacking of DOC and CDOC is more enantioselective than the stacking of SC on the SWCNT walls, while SC has a clear diameter preference for efficiently solubilizing the SWCNTs in comparison to DOC and CDOC. Moreover, combining sodium dodecylsulfate with SC allows for resolving the ATPE sorting transitions of empty and water-filled SWCNTs for a number of SWCNT chiralities. We also show that addition of SC to combinations of DOC and sodium dodecylbenzenesulfonate can enhance separations of particular chiralities.

| S-EPMC9612395 | biostudies-literature

Sorting and decoration of semiconducting single-walled carbon nanotubes via the quaternization reaction.

Project description:A study for the selective separation and functionalization of alcohol-soluble semiconducting single-walled carbon nanotubes (sc-SWCNTs) is carried out by polymer main-chain engineering. Introducing tertiary amine groups endows the functionalized sc-SWCNTs with alcohol-soluble properties and introducing the pyrimidine rings allows to increase the selective purity of sc-SWCNTs. In this study, a series of poly[(9,9-dioctylfluorene)-2,7-(9,9-bis(3'-(N,N-dimethylamino)propyl)-fluorene)] m -alt-[2-methylpyrimidine-2,7-(9,9-dioctylfluorene)] n (PFPy) are used for the selective dispersion of semiconducting single-walled carbon nanotubes, where n and m are the composition ratio of the copolymer. When m = n, the effective isolation of sc-SWCNTs with purity greater than 99% is achieved. The alcohol-soluble sc-SWCNTs with a diameter in the range of 1.1-1.4 nm are obtained through designing reasonable molecular structure. Moreover, the particular preference of PFPy (m = n) for sc-SWCNTs was studied via density functional theory (DFT) calculations and it was proved to be a promising method for the separation and functionalization of sc-SWCNTs.

| S-EPMC8693859 | biostudies-literature

Aqueous-phase synthesis of monodisperse plasmonic gold nanocrystals using shortened single-walled carbon nanotubes.

Project description:Monodisperse gold nanocrystals with unique near-infrared optical properties were synthesized by simple mixing of highly shortened and well disperse single-walled carbon nanotubes and chloroauric acid in water at ambient conditions with a step-wise increase of gold ion concentration.

| S-EPMC4321945 | biostudies-literature

Adsorption of tetracycline from aqueous solutions onto multi-walled carbon nanotubes with different oxygen contents.

Project description:Oxidized multi-walled carbon nanotubes (MWCNTs) with different oxygen contents were investigated for the adsorption of tetracycline (TC) from aqueous solutions. As the surface oxygen content of the MWCNTs increased, the maximum adsorption capacity and adsorption coefficient of TC increased to the largest values and then decreased. The relation can be attributed to the interplay between the nanotubes' dispersibility and the water cluster formation upon TC adsorption. The overall adsorption kinetics of TC onto CNTs-3.2%O might be dependent on both intra-particle diffusion and boundary layer diffusion. The maximum adsorption capacity of TC on CNTs-3.2%O was achieved in the pH range of 3.3-8.0 due to formation of water clusters or H-bonds. Furthermore, the presence of Cu(2+) could significantly enhanced TC adsorption at pH of 5.0. However, the solution ionic strength did not exhibit remarkable effect on TC adsorption. In addition, when pH is beyond the range (3.3-8.0), the electrostatic interactions caused the decrease of TC adsorption capacity. Our results indicate that surface properties and aqueous solution chemistry play important roles in TC adsorption on MWCNTs.

| S-EPMC4060509 | biostudies-literature

One step fabrication of aligned carbon nanotubes using gas rectifier.

Project description:We report the one-step fabrication of aligned and high-quality carbon nanotubes (CNTs) using floating-catalyst chemical vapor deposition (FCCVD) with controlled fluidic properties assisted by a gas rectifier. The gas rectifier consists of one-dimensional straight channels for regulating the Reynolds number of the reaction gas. Our computational fluid dynamics simulation reveals that the narrow channels of the gas rectifier provide steady and accelerated laminar flow of the reaction gas. In addition, strong shear stress is induced near the side wall of the channels, resulting in the spontaneous formation of macroscopic CNT bundles aligned along the direction of the gas flow. After a wet-process using chlorosulfonic acid, the inter-tube voids inherently observed in as-grown CNT bundles are reduced from 16 to 0.3%. The resulting CNT fiber exhibits a tensile strength of 2.1 ± 0.1 N tex-1 with a Young's modulus of 39 ± 4 N tex-1 and an elongation of 6.3 ± 0.6%. FCCVD coupled with the strong shear stress of the reaction gas is an important pre-processing route for the fabrication of high-performance CNT fibers.

| S-EPMC8789815 | biostudies-literature

One-step extraction and concentration of estrogens for an adequate monitoring of wastewater using ionic-liquid-based aqueous biphasic systems.

Project description:Ethinylestradiol (EE2) is a synthetic hormone that has been recognized as one of the most prominent endocrine disruptors found in the aqueous environment. Nevertheless, the low content of EE2 in wastewater makes its identification/quantification unfeasible - a major drawback for the evaluation of its persistence and environmental impact. In this context, a novel extraction/concentration method for EE2 from wastewater is proposed here based on aqueous biphasic systems composed of ionic liquids (ILs). Aqueous biphasic systems formed by several hydrophilic ILs and KNaC4H4O6 were initially screened and optimized, with extraction efficiencies of EE2 for the IL-rich phase ranging between 92 and 100%. Remarkable results were obtained with systems that allow the complete extraction of EE2 in a single-step, and without loss of EE2 or the saturation of the extractive phase. Further, the concentration factors of EE2 attainable with these systems were investigated by a suitable manipulation of the composition of the phase-forming components and the corresponding volumes of the coexisting phases. An outstanding concentration of EE2 up to 1000-fold (from ng L-1 to μg L-1) in a single extraction and concentration step was achieved for the first time with IL-based aqueous biphasic systems. These systems are straightforwardly envisaged for the monitoring of wastewater as one-step extraction and concentration routes for a wide array of endocrine disrupting chemicals while allowing an adequate evaluation of their environmental impact.

| S-EPMC4568319 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data