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Leading Interaction Components in the Structure and Reactivity of Noble Gases Compounds.

ABSTRACT: The nature, strength, range and role of the bonds in adducts of noble gas atoms with both neutral and ionic partners have been investigated by exploiting a fine-tuned integrated phenomenological-theoretical approach. The identification of the leading interaction components in the noble gases adducts and their modeling allows the encompassing of the transitions from pure noncovalent to covalent bound aggregates and to rationalize the anomalous behavior (deviations from noncovalent type interaction) pointed out in peculiar cases. Selected adducts affected by a weak chemical bond, as those promoting the formation of the intermolecular halogen bond, are also properly rationalized. The behavior of noble gas atoms excited in their long-life metastable states, showing a strongly enhanced reactivity, has been also enclosed in the present investigation.

SUBMITTER: Nunzi F

PROVIDER: S-EPMC7287633 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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Leading Interaction Components in the Structure and Reactivity of Noble Gases Compounds.

Nunzi Francesca F Pannacci Giacomo G Tarantelli Francesco F Belpassi Leonardo L Cappelletti David D Falcinelli Stefano S Pirani Fernando F

Molecules (Basel, Switzerland) 20200520 10

The nature, strength, range and role of the bonds in adducts of noble gas atoms with both neutral and ionic partners have been investigated by exploiting a fine-tuned integrated phenomenological-theoretical approach. The identification of the leading interaction components in the noble gases adducts and their modeling allows the encompassing of the transitions from pure noncovalent to covalent bound aggregates and to rationalize the anomalous behavior (deviations from noncovalent type interactio ...[more]

PMID: 32443725

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Author Correction: Noble gases confirm plume-related mantle degassing beneath Southern Africa.

Project description: Not available

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