Dataset Information

Transition between solid and liquid state of yield-stress fluids under purely extensional deformations.

ABSTRACT: We report experimental microfluidic measurements and theoretical modeling of elastoviscoplastic materials under steady, planar elongation. Employing a theory that allows the solid state to deform, we predict the yielding and flow dynamics of such complex materials in pure extensional flows. We find a significant deviation of the ratio of the elongational to the shear yield stress from the standard value predicted by ideal viscoplastic theory, which is attributed to the normal stresses that develop in the solid state prior to yielding. Our results show that the yield strain of the material governs the transition dynamics from the solid state to the liquid state. Finally, given the difficulties of quantifying the stress field in such materials under elongational flow conditions, we identify a simple scaling law that enables the determination of the elongational yield stress from experimentally measured velocity fields.

SUBMITTER: Varchanis S

PROVIDER: S-EPMC7293695 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Publications

Transition between solid and liquid state of yield-stress fluids under purely extensional deformations.

Varchanis Stylianos S Haward Simon J SJ Hopkins Cameron C CC Syrakos Alexandros A Shen Amy Q AQ Dimakopoulos Yannis Y Tsamopoulos John J

Proceedings of the National Academy of Sciences of the United States of America 20200520 23

We report experimental microfluidic measurements and theoretical modeling of elastoviscoplastic materials under steady, planar elongation. Employing a theory that allows the solid state to deform, we predict the yielding and flow dynamics of such complex materials in pure extensional flows. We find a significant deviation of the ratio of the elongational to the shear yield stress from the standard value predicted by ideal viscoplastic theory, which is attributed to the normal stresses that devel ...[more]

PMID: 32434919

Similar Datasets

Project description:Ionic liquids (ILs) hold great potential as solvents to dissolve, recycle, and regenerate cellulosic fabrics, but the dissolved cellulose material system requires greater study in conditions relevant to fiber spinning processes, especially characterization of nonlinear shear and extensional flows. To address this gap, we aimed to disentangle the effects of the temperature, cellulose concentration, and degree of polymerization (DOP) on the shear and extensional flows of cellulose dissolved in an IL. We have studied the behavior of cellulose from two sources, fabric and filter paper, dissolved in 1-ethyl-3-methylimidazolium acetate ([C2C1Im][OAc]) over a range of temperatures (25 to 80 °C) and concentrations (up to 4%) that cover both semidilute and entangled regimes. The linear viscoelastic (LVE) response was measured using small-amplitude oscillatory shear techniques, and the results were unified by reducing the temperature, concentration, and DOP onto a single master curve using time superposition techniques. The shear rheological data were further fitted to a fractional Maxwell liquid (FML) model and were found to satisfy the Cox-Merz rule within the measurement range. Meanwhile, the material response in the non-LVE (NLVE) regime at large strains and strain rates has special relevance for spinning processes. We quantified the NLVE behavior using steady shear flow tests alongside uniaxial extension using a customized capillary breakup extensional rheometer. The results for both shear and extensional NLVE responses were described by the Rolie-Poly model to account for flow-dependent relaxation times and nonmonotonic viscosity evolution with strain rates in an extensional flow, which primarily arise from complex polymer interactions at high concentrations. The physically interpretable model fitting parameters were further compared to describe differences in material response to different flow types at varying temperatures, concentrations, and DOP. Finally, the fitting parameters from the FML and Rolie-Poly models were connected under the same superposition framework to provide a comprehensive description within the wide measured parameter window for the flow and handling of cellulose in [C2C1Im][OAc] in both linear and nonlinear regimes.

Dataset Information

Transition between solid and liquid state of yield-stress fluids under purely extensional deformations.

Publications

Transition between solid and liquid state of yield-stress fluids under purely extensional deformations.

Similar Datasets

OmicsDI is part of the ELIXIR infrastructure

Tweets