Dataset Information

Asphaltene Adsorption on Functionalized Solids.

ABSTRACT: Asphaltenes, heavy aromatic components of crude oil, are known to adsorb on surfaces and can lead to pipe clogging or hinder oil recovery. Because of their multicomponent structure, the details of their interactions with surfaces are complex. We investigate the effect of the physicochemical properties of the substrate on the extent and mechanism of this adsorption. Using wetting measurements, we relate the initial kinetics of deposition to the interfacial energy of the surface. We then quantify the long-term adsorption dynamics using a quartz crystal microbalance and ellipsometry. Finally, we investigate the mechanism and morphology of adsorption with force spectroscopy measurements as a function of surface chemistry. We determine different adsorption regimes differing in orientation, packing density, and initial kinetics on different substrate functionalizations. Specifically, we find that alkane substrates delay the initial monolayer formation, fluorinated surfaces exhibit fast adsorption but low bonding strength, and hydroxyl substrates lead to a different adsorption orientation and a high packing density of the asphaltene layer.

SUBMITTER: Girard HL

PROVIDER: S-EPMC7307966 | biostudies-literature | 2020 Apr

REPOSITORIES: biostudies-literature

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Asphaltene Adsorption on Functionalized Solids.

Girard Henri-Louis HL Bourrianne Philippe P Chen Dayong D Jaishankar Aditya A Vreeland Jessica L JL Cohen Robert E RE Varanasi Kripa K KK McKinley Gareth H GH

Langmuir : the ACS journal of surfaces and colloids 20200402 14

Asphaltenes, heavy aromatic components of crude oil, are known to adsorb on surfaces and can lead to pipe clogging or hinder oil recovery. Because of their multicomponent structure, the details of their interactions with surfaces are complex. We investigate the effect of the physicochemical properties of the substrate on the extent and mechanism of this adsorption. Using wetting measurements, we relate the initial kinetics of deposition to the interfacial energy of the surface. We then quantify ...[more]

PMID: 32090578

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Project description:In recent years, researchers have attempted to find some practical approaches for asphaltene adsorption and the prevention or postponement of asphaltene precipitation. Among different techniques, nanotechnology has attracted the researchers' attention to overcome the formation damage resulting from the deposition of asphaltenes. In this study, the application of two types of carboxylate-alumoxane nanoparticles (functionalized boehmite by methoxyacetic acid (BMA) and functionalized pseudo-boehmite by methoxyacetic acid (PBMA)) for asphaltene adsorption and precipitation was investigated. First, the synthesis of two functionalized nanoparticles was performed via the sol-gel method. For the assessment of the adsorption efficiency and adsorption capacity of these nanoparticles toward asphaltene adsorption, the batch adsorption experiments applying ultraviolet-visible (UV-Vis) spectroscopy were performed. The Langmuir and Freundlich isotherms were studied to describe the interaction between asphaltene molecules and carboxylate-alumoxane nanoparticles. For determining the "onset" point of asphaltene precipitation, the indirect method, which was based on the difference in the optical property of various solutions containing different concentrations of asphaltene, was utilized by applying UV-Vis spectroscopy. The isotherm models indicate that the adsorption of asphaltene on the surface of nanoparticles is better fitted to the Freundlich isotherm model compared with the Langmuir model. In the presence of PBMA (0.1 wt %), the onset point was delayed around 26, 20, and 17% in the asphaltene concentrations of 1000, 3000, and 5000 ppm, respectively, in comparison with their reference synthetic oils. On the other hand, these postponements for BMA nanoparticles (0.1 wt %) were 17%, 9%, and insignificant for the asphaltene concentrations of 1000, 3000, and 5000 ppm, respectively. The results reveal that two functionalized nanoparticles tend to adsorb asphaltene molecules and have a positive impact on the postponement of asphaltene precipitation due to molecular interactions between the surface of carboxylate-alumoxane nanoparticles and asphaltene molecules. However, PBMA nanoparticles exhibited better performance on the asphaltene adsorption and postponement of asphaltene precipitation, which is related to its smaller size, as well as higher surface area, compared with BMA nanoparticles.

Dataset Information

Asphaltene Adsorption on Functionalized Solids.

Publications

Asphaltene Adsorption on Functionalized Solids.

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