Ultrafine CoP/Co₂P Nanorods Encapsulated in Janus/Twins-type Honeycomb 3D Nitrogen-Doped Carbon Nanosheets for Efficient Hydrogen Evolution.

ABSTRACT: In this study, we report a Janus- or twins-type honeycomb 3D porous nitrogen-doped carbon (NC) nanosheet array encapsulating ultrafine CoP/Co₂P nanorods supported on Ti foil (CoP/Co₂P@NC/Ti) as a self-supported electrode for efficient hydrogen evolution. The synthesis and formation mechanism of 3D porous NC nanosheet array assembled into a honeycomb layer with ultrafine CoP/Co₂P single-crystal nanorods encapsulated is systematically presented. The CoP/Co₂P@NC/Ti electrode exhibits low overpotentials (?₁₀) of 31, 49, and 64 mV at a current density of -10 mA cm^-2 in 0.5 M H₂SO₄, 1.0 KOH, and 1.0 M PBS, respectively, exceeding the overwhelming majority of the documented transition metal phosphide-based electrocatalysts. Density functional theory calculation reveals that the superior electrocatalytic performance for hydrogen evolution reaction could be ascribed to the strong coupling effects of the reactive facets of CoP and Co₂P with the 3D porous NC nanosheet, making it exhibit a more thermo-neutral hydrogen adsorption free energy.

SUBMITTER: Liu B 

PROVIDER: S-EPMC7326735 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature