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Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne.

ABSTRACT: Light elements in the interstitial site of transition metals have strong influence on heterogeneous catalysis via either expression of surface structures or even direct participation into reaction. Interstitial atoms are generally metastable with a strong environmental dependence, setting up giant challenges in controlling of heterogeneous catalysis. Herein, we show that the desired carbon atoms can be manipulated within nickel (Ni) lattice for improving the selectivity in acetylene hydrogenation reaction. The radius of octahedral space of Ni is expanded from 0.517 to 0.524 Å via formation of Ni₃Zn, affording the dissociated carbon atoms to readily dissolve and diffuse at mild temperatures. Such incorporated carbon atoms coordinate with the surrounding Ni atoms for generation of Ni₃ZnC_0.7 and thereof inhibit the formation of subsurface hydrogen structures. Thus, the selectivity and stability are dramatically improved, as it enables suppressing the pathway of ethylene hydrogenation and restraining the accumulation of carbonaceous species on surface.

SUBMITTER: Niu Y

PROVIDER: S-EPMC7335178 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature

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Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne.

Niu Yiming Y Huang Xing X Wang Yongzhao Y Xu Ming M Chen Junnan J Xu Shuliang S Willinger Marc-Georg MG Zhang Wei W Wei Min M Zhang Bingsen B

Nature communications 20200703 1

Light elements in the interstitial site of transition metals have strong influence on heterogeneous catalysis via either expression of surface structures or even direct participation into reaction. Interstitial atoms are generally metastable with a strong environmental dependence, setting up giant challenges in controlling of heterogeneous catalysis. Herein, we show that the desired carbon atoms can be manipulated within nickel (Ni) lattice for improving the selectivity in acetylene hydrogenatio ...[more]

PMID: 32620829

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Project description:Background: Optical microtraps at the focus of high numerical aperture (high-NA) imaging systems enable efficient collection, trapping, detection and manipulation of individual neutral atoms for quantum technology and studies of optical physics associated with super- and sub-radiant states. The recently developed "Maltese cross" geometry (MCG) atom trap uses four in-vacuum lenses to achieve four-directional high-NA optical coupling to single trapped atoms and small atomic arrays. This article presents the first extensive characterisation of atomic behaviour in a MCG atom trap. Methods: We employ a MCG system optimised for high coupling efficiency and characterise the resulting properties of the trap and trapped atoms. Using current best practices, we measure occupancy, loading rate, lifetime, temperature, fluorescence anti-bunching and trap frequencies. We also use the four-directional access to implement a new method to map the spatial distribution of collection efficiency from high-NA optics: we use the two on-trap-axis lenses to produce a 1D optical lattice, the sites of which are stochastically filled and emptied by the trap loading process. The two off-trap-axis lenses are used for imaging and single-mode collection. Correlations of single-mode and imaging fluorescence signals are then used to map the single-mode collection efficiency. Results: We observe trap characteristics comparable to what has been reported for single-atom traps with one- or two-lens optical systems. The collection efficiency distribution in the axial and transverse directions is directly observed to be in agreement with expected collection efficiency distribution from Gaussian beam optics. Conclusions: The multi-directional high-NA access provided by the Maltese cross geometry enables complex manipulations and measurements not possible in geometries with fewer directions of access, and can be achieved while preserving other trap characteristics such as lifetime, temperature, and trap size.

Dataset Information

Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne.

Publications

Manipulating interstitial carbon atoms in the nickel octahedral site for highly efficient hydrogenation of alkyne.

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