Crystal structure and Hirshfeld surface analysis of 4-{[(E)-4-(hept-yloxy)benzyl-idene]amino}-N-(naphthalen-2-yl)-1,3-thia-zol-2-amine.

ABSTRACT: In the title compound, C27H28N2OS, the naphthalene unit is planar to within 0.015?(2)?Å and makes a dihedral angle of 14.24?(16)° with the thia-zole ring. The anisole ring is inclined to the thia-zole ring by a dihedral angle of 13.18?(23)°. The torsion angle between the heptyl chain and the anisole ring is 61.1?(4)°. These dihedral and torsion angles render the mol-ecule non-planar. In the crystal, mol-ecules are linked by C-H?? inter-actions, forming zigzag chains that propagate parallel to the b axis. The roles of the various inter-molecular inter-actions in the crystal packing were clarified by Hirshfeld surface analysis; the most important contributions are from H?H (51.5%) and C?H/H?C (31.8%) contacts.

SUBMITTER: Sheakh Mohamad RA 

PROVIDER: S-EPMC7336791 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature