3D-printed graphene/polymer structures for electron-tunneling based devices.

ABSTRACT: Designing 3D printed micro-architectures using electronic materials with well-understood electronic transport within such structures will potentially lead to accessible device fabrication for 'on-demand' applications. Here we show controlled nozzle-extrusion based 3D printing of a commercially available nano-composite of graphene/polylactic acid, enabling the fabrication of a tensile gauge functioning via the readjustment of the electron-tunneling barrier width between conductive graphene-centers. The electronic transport in the graphene/polymer 3D printed structure exhibited the Fowler Nordheim mechanism with a tunneling width of 0.79-0.95 nm and graphene centers having a carrier concentration of 2.66?×?10¹²/cm². Furthermore, a mechanical strain that increases the electron-tunneling width between graphene nanostructures (~?38 nm) by only 0.19 ? reduces the electron flux by 1e/s/nm² (from 18.51 to 19.51 e/s/nm²) through the polylactic acid junctions in the 3D-printed heterostructure. This corresponds to a sensitivity of 2.59 ?/?%, which compares well with other tensile gauges. We envision that the proposed electron-tunneling model for conductive 3D-printed structures with thermal expansion and external strain will lead to an evolution in the design of next-generation of 'on-demand' printed electronic and electromechanical devices.

SUBMITTER: Carvalho Fernandes DC 

PROVIDER: S-EPMC7347914 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature