Synthesis of Ir^III Hydrido Complexes by Oxidative Addition of Halogenated Theophylline and Adenine Derivatives.

ABSTRACT: The Ir^III hydrido complexes [1] and [2] have been synthesized by the regioselective oxidative addition of the N7-H bond of 8-halogenotheophyllines to [IrCl(coe)₂]₂ in the presence of PPh₃. The use of dppf in this reaction yielded the bimetallic Ir^III/Fe^II hydrido complexes [3] and [4]. X-ray diffraction studies confirmed that complexes [1]-[4] feature a theophyllinato ligand coordinated to the metal center in the rarely observed, chelating fashion via the N7 and O1 atoms. In addition, 8-bromoadenine reacts with [IrCl(coe)₂]₂ in the presence of PPh₃ to form the Ir^III hydrido complex [5] which features one anionic 8-bromoadeninato and

SUBMITTER: Blumenberg J 

PROVIDER: S-EPMC7366355 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature