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Crystal structure of an ordered [WOF5]- salt: (1,10-phen-H)[WOF5] (1,10-phen = 1,10-phenanthroline).


ABSTRACT: Crystals of 1,10-phenanthrolinium penta-fluorido-oxidotungstate(VI), (1,10-phen-H)[WOF5] (1,10-phen = 1,10-phenanthroline, C12H8N2), were obtained upon hydrolysis of WF6(1,10-phen) in CH3CN at 193?K. The (1,10-phen-H)[WOF5] salt contains a rare example of a [WOF5]- anion in which the oxygen and fluorine atoms are ordered. This ordering was verified by bond-valence determinations and structural comparisons with [Xe2F11][WOF5] and Lewis acid-base adducts of WOF4 with main-group donor ligands. The crystal packing is controlled by N-H?F hydrogen bonding that is directed exclusively to the axial F atom as a result of its increased basicity caused by the trans influence of the oxido ligand.

SUBMITTER: Turnbull D 

PROVIDER: S-EPMC7405552 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature

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Crystal structure of an ordered [WOF<sub>5</sub>]<sup>-</sup> salt: (1,10-phen-H)[WOF<sub>5</sub>] (1,10-phen = 1,10-phenanthroline).

Turnbull Douglas D   Gerken Michael M  

Acta crystallographica. Section E, Crystallographic communications 20200724 Pt 8


Crystals of 1,10-phenanthrolinium penta-fluorido-oxidotungstate(VI), (1,10-phen-H)[WOF<sub>5</sub>] (1,10-phen = 1,10-phenanthroline, C<sub>12</sub>H<sub>8</sub>N<sub>2</sub>), were obtained upon hydrolysis of WF<sub>6</sub>(1,10-phen) in CH<sub>3</sub>CN at 193 K. The (1,10-phen-H)[WOF<sub>5</sub>] salt contains a rare example of a [WOF<sub>5</sub>]<sup>-</sup> anion in which the oxygen and fluorine atoms are ordered. This ordering was verified by bond-valence determinations and structural comp  ...[more]

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