Ontology highlight
ABSTRACT:
SUBMITTER: Turnbull D
PROVIDER: S-EPMC7405552 | biostudies-literature | 2020 Aug
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20200724 Pt 8
Crystals of 1,10-phenanthrolinium penta-fluorido-oxidotungstate(VI), (1,10-phen-H)[WOF<sub>5</sub>] (1,10-phen = 1,10-phenanthroline, C<sub>12</sub>H<sub>8</sub>N<sub>2</sub>), were obtained upon hydrolysis of WF<sub>6</sub>(1,10-phen) in CH<sub>3</sub>CN at 193 K. The (1,10-phen-H)[WOF<sub>5</sub>] salt contains a rare example of a [WOF<sub>5</sub>]<sup>-</sup> anion in which the oxygen and fluorine atoms are ordered. This ordering was verified by bond-valence determinations and structural comp ...[more]