Improvement of the Battery Performance of Indigo, an Organic Electrode Material, Using PEDOT/PSS with d-Sorbitol.

ABSTRACT: Rare-metal-free and high-performance secondary batteries are necessary for improving the efficiency of renewable energy systems. Organic compounds are attractive candidates for the active material of such batteries. Many studies have reported organic active materials that show high energy density per active material weight. However, organic active materials, most of which exhibit low conductivity and low specific density, typically require a large amount of a conductive additive (>50 wt %) to obtain a high utilization rate. Therefore, organic active materials rarely display high energy density per electrode weight. High energy densities per electrode weight can be obtained using high weight fractions of active materials and low weight fractions of conductive additives. Herein, we report that a low-conductivity organic active material, indigo, showed improved net discharge capacity density when even a small amount of a conductive polymer composite, poly(3,4-ethylenedioxythiophene)/polystyrene sulfonic acid (PEDOT/PSS) with d-sorbitol, was used as both a binder and conductive additive. The cycle life was also improved by coating one side of the separator with the composite, which probably hindered the dissolution of the active material. A discharge capacity of 96% of the theoretical capacity of indigo and an improved cycle life were achieved with an electrode containing 80 wt % indigo and with a PEDOT/PSS-coated separator. The optimal fraction of the conductive binder was examined, and the mechanism of conductivity enhancement was discussed. The present scheme allows us to replace the dispersion solvent of the slurry, N-methylpyrrolidone, with water, which can reduce the environmental load during battery manufacturing processes.

SUBMITTER: Kato M 

PROVIDER: S-EPMC7407543 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature