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Diastereoselective peroxidation of derivatives of Baylis-Hillman adducts.

ABSTRACT: Cyclic derivatives of Baylis-Hillman adducts were synthesized. Cobalt-catalyzed peroxidation of these cyclic lactones afforded silyl peroxides in diastereomeric ratios ranging from 91:9 to 97:3.

SUBMITTER: Zuckerman DS 

PROVIDER: S-EPMC7437930 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature

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Diastereoselective peroxidation of derivatives of Baylis-Hillman adducts.

Zuckerman Dylan S DS   Woerpel K A KA  

Tetrahedron 20190509 31

Cyclic derivatives of Baylis-Hillman adducts were synthesized. Cobalt-catalyzed peroxidation of these cyclic lactones afforded silyl peroxides in diastereomeric ratios ranging from 91:9 to 97:3. ...[more]

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