(8-Amino)quinoline and (4-Amino)phenanthridine Complexes of Re(CO)₃ Halides.

ABSTRACT: In this report, we present a study on the synthesis, structure, and electronics of a series of (8-amino)quinoline and (4-amino)phenanthridine complexes of Re(CO)₃X, where X = Cl and Br. In all cases, the (amino)heterocycles bind as bidentate ligands, with surprisingly symmetric modes of binding based on Re-N bond lengths. Between the complexes of (8-amino)quinolines and (4-amino)phenanthridines studied in this report, we do not observe much structural variation, and remarkably similar UV-visible absorption spectra. Expansion of the π-system in the (4-amino)phenanthridine complexes does result in an increase in the intensity of the lowest energy transitions (λ_max), which computational modeling suggests are more purely MLCT in character compared with the mixed π-π*/MLCT

SUBMITTER: Gaire S 

PROVIDER: S-EPMC7442205 | biostudies-literature | 2020 Aug

REPOSITORIES: biostudies-literature