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Silver-Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions.

ABSTRACT: A silver-triggered heterogeneous Pd-catalyzed oxidative carbonylation has been developed. This heterogeneous process exhibits high efficiency and good recyclability, and was utilized for the one-pot construction of polycyclic compounds with multiple chiral centers. AgOTf was used to remove chloride ions in the heterogeneous catalyst Pd-AmP-CNC, thereby generating highly active PdII , which results in high efficiency of the heterogeneous catalytic system.

SUBMITTER: Li MB

PROVIDER: S-EPMC7463174 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature

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Silver-Triggered Activity of a Heterogeneous Palladium Catalyst in Oxidative Carbonylation Reactions.

Li Man-Bo MB Yang Ying Y Rafi Abdolrahim A AA Oschmann Michael M Grape Erik Svensson ES Inge A Ken AK Córdova Armando A Bäckvall Jan-E JE

Angewandte Chemie (International ed. in English) 20200407 26

A silver-triggered heterogeneous Pd-catalyzed oxidative carbonylation has been developed. This heterogeneous process exhibits high efficiency and good recyclability, and was utilized for the one-pot construction of polycyclic compounds with multiple chiral centers. AgOTf was used to remove chloride ions in the heterogeneous catalyst Pd-AmP-CNC, thereby generating highly active Pd<sup>II</sup> , which results in high efficiency of the heterogeneous catalytic system. ...[more]

PMID: 32091647

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