Ontology highlight
ABSTRACT:
SUBMITTER: Halter DP
PROVIDER: S-EPMC7473405 | biostudies-literature | 2020 Jul
REPOSITORIES: biostudies-literature
Halter Dominik P DP Klein Ryan A RA Boreen Michael A MA Trump Benjamin A BA Brown Craig M CM Long Jeffrey R JR
Chemical science 20200527 26
A new, air-stable, permanently porous uranium(iv) metal-organic framework U(bdc)<sub>2</sub> (<b>1</b>, bdc<sup>2-</sup> = 1,4-benzenedicarboxylate) was synthesized and its H<sub>2</sub> and CH<sub>4</sub> adsorption properties were investigated. Low temperature adsorption isotherms confirm strong adsorption of both gases in the framework at low pressures. <i>In situ</i> gas-dosed neutron diffraction experiments with different D<sub>2</sub> loadings revealed a rare example of cooperative framewo ...[more]