Ontology highlight
ABSTRACT:
SUBMITTER: Heidrich M
PROVIDER: S-EPMC7476583 | biostudies-literature | 2020
REPOSITORIES: biostudies-literature
Beilstein journal of organic chemistry 20200826
The efficient hydrohydrazidation of terminal (<b>6a</b>-<b>r</b>, 18 examples, 0.1-0.2 mol % [(NHC)Au(NTf<sub>2</sub>)], <i>T</i> = 60 °C) and internal alkynes (<b>7a</b>-<b>j</b>, 10 examples, 0.2-0.5 mol % [(NHC)Au(NTf<sub>2</sub>)], <i>T</i> = 60-80 °C) utilizing a complex with a sterically demanding bispentiptycenyl-substituted NHC ligand and the benign reaction solvent anisole, is reported. ...[more]