Ontology highlight
ABSTRACT:
SUBMITTER: Gracia LL
PROVIDER: S-EPMC7497214 | biostudies-literature | 2020 Jul
REPOSITORIES: biostudies-literature
Chemistry (Weinheim an der Bergstrasse, Germany) 20200716 44
Earth-abundant metal complexes have been attracting increasing attention in the field of photo(redox)catalysis. In this work, the synthesis and full characterisation of four new heteroleptic Cu<sup>I</sup> complexes are reported, which can work as photosensitizers. The complexes bear a bulky diphosphine (DPEPhos=bis[(2-diphenylphosphino)phenyl] ether) and a diimine chelating ligand based on 1-benzyl-4-(quinol-2'yl)-1,2,3-triazole. Their absorption has a relative maximum in the visible-light regi ...[more]