Crystal structure of [{[Ni(C₁₀H₂₄N₄)][Ni(CN)₄]}·2H₂O] _n , a one-dimensional coordination polymer formed from the [Ni(cyclam)]²⁺ cation and the [Ni(CN)₄]^2- anion.

ABSTRACT: The asymmetric unit of the title compound, catena-poly[[[(1,4,8,11-tetra-aza-cyclo-tetra-decane-κ⁴ N ¹,N ⁴,N ⁸,N ¹¹)nickel(II)]-μ-cyanido-κ² N:C-[bis-(cyanido-κC)nickel(II)]-μ-cyanido-κ² C:N] dihydrate], {[Ni₂(CN)₄(C₁₀H₂₄N₄)]·2H₂O] _n or [{[Ni(C₁₀H₂₄N₄)][Ni(CN)₄]}·2H₂O] _n , consists of a pair of crystallographically non-equivalent macrocyclic cations and anions. The nickel(II) ions (all with site symmetry ) are coordinated by the four secondary N atoms of the macrocyclic ligands, which adopt

SUBMITTER: Tsymbal LV 

PROVIDER: S-EPMC8587981 | biostudies-literature | 2021 Nov

REPOSITORIES: biostudies-literature