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Rare A-Type, Spiro-Type, and Highly Oligomeric Proanthocyanidins from Pinus massoniana.

ABSTRACT: An investigation of the dental bioactive proanthocyanidin (PAC) oligomer fractions led to three structurally distinct new PACs (1-3) from pine bark. Pinutwindoublin (1) is the first reported trimer with double A-type interflavanyl linkages (2α→O→5,4α→6 and 2α→O→7,4α→8). Pinuspirotetrin (2) represents the first reported PAC tetramer with a heterodimeric framework consisting of one spiro-type and one A-type dimer. Pinumassohexin (3) was elucidated as a mixed A + B-type hexamer that consists of a peanut-derived tetramer, peanut procyanidin E, and an A-type dimer (5). Compound 3 increased the modulus of elasticity of dentin by an impressive 4.3 times at a concentration of 0.65%.

SUBMITTER: Zhou B

PROVIDER: S-EPMC7521950 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Tri- and Tetrameric Proanthocyanidins with Dentin Bioactivities from <i>Pinus massoniana</i>.

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