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Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing.

ABSTRACT: A novel triazene-anthracene-based fluorescent aminal linked porous organic polymer (TALPOP) was prepared via metal free-Schiff base polycondensation reaction of 9,10-bis-(4,6-diamino-S-triazin-2-yl)anthracene and 2-furaldehyde. The polymer has exceptional chemical and thermal stabilities and exhibit good porosity with Brunauer-Emmett-Teller surface area of 401 m²g^-1. The combination of such porosity along with the highly conjugated heteroatom-rich framework enabled the polymer to exhibit exceptional iodine vapor uptake of up to 314 wt % and reversible iodine adsorption in solution. Because of the inclusion of the anthracene moieties, the TALPOP exhibited excellent detection sensitivity towards iodine via florescence quenching with K_sv value of 2.9?×?10³ L mol^-1. The cost effective TALPOP along with its high uptake and sensing of iodine, make it an ideal material for environmental remediation.

SUBMITTER: Sabri MA

PROVIDER: S-EPMC7525493 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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Fluorescent aminal linked porous organic polymer for reversible iodine capture and sensing.

Sabri Muhammad A MA Al-Sayah Mohammad H MH Sen Susan S Ibrahim Taleb H TH El-Kadri Oussama M OM

Scientific reports 20200929 1

A novel triazene-anthracene-based fluorescent aminal linked porous organic polymer (TALPOP) was prepared via metal free-Schiff base polycondensation reaction of 9,10-bis-(4,6-diamino-S-triazin-2-yl)anthracene and 2-furaldehyde. The polymer has exceptional chemical and thermal stabilities and exhibit good porosity with Brunauer-Emmett-Teller surface area of 401 m2g-1. The combination of such porosity along with the highly conjugated heteroatom-rich framework enabled the poly ...[more]

PMID: 32994515

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