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PH-Responsive Host-Guest Complexations Between a Water-Soluble Pillar[6]arene Dodecyl-Ammonium Chloride and Aromatic Sulfonic Acids.


ABSTRACT: In the present work, new host-guest binding motifs based on a water-soluble pillar[6]arene dodecyl-ammonium chloride (CP6) with two aromatic sulfonic acids in aqueous media were fabricated. In accordance with the integrated results of 1H NMR, 2D NOESY, and florescence titration experiments, it was demonstrated that the host-guest binding of CP6 with the two aromatic sulfonic acids in aqueous solution not only has high binding constants but also has pH-responsiveness.

SUBMITTER: Duan Q 

PROVIDER: S-EPMC7533581 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature

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pH-Responsive Host-Guest Complexations Between a Water-Soluble Pillar[6]arene Dodecyl-Ammonium Chloride and Aromatic Sulfonic Acids.

Duan Qunpeng Q   Wang Fei F   Zhang Hongsong H   Lu Kui K  

Frontiers in chemistry 20200915


In the present work, new host-guest binding motifs based on a water-soluble pillar[6]arene dodecyl-ammonium chloride (CP6) with two aromatic sulfonic acids in aqueous media were fabricated. In accordance with the integrated results of <sup>1</sup>H NMR, 2D NOESY, and florescence titration experiments, it was demonstrated that the host-guest binding of CP6 with the two aromatic sulfonic acids in aqueous solution not only has high binding constants but also has pH-responsiveness. ...[more]

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