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Differentiation Between Metronidazole Residues Disposal by Using Adsorption and Photodegradation Processes Onto MgO Nanoparticles

ABSTRACT: Background Metronidazole (MNZ) is an antibiotic form that is considered as a dangerous environmental pollutant due to its widespread use as growth promoters in livestock and aquaculture operations along with its therapeutic application for humans. Purpose The objective of this work was to conduct a comparative study between the efficiency of the adsorption and photocatalytic degradation of MNZ in an aqueous solution by using magnesium oxide nanoparticles (MgO NP) under different effects, as well as evaluate the performance, reusability and cost study. Materials and Methods Several instruments such as XRD, EDX, SEM, and TEM were used to characterize the chemical composition and morphological properties of the synthesized MgO NP, while the GC-MS analysis was used to monitor the degradation pathway of MNZ particles within 180 min. The simple photo-batch reactor was used to investigate the degradation of MNZ under the effect of UV radiation, initial concentration of MNZ, pH, catalyst loading, inorganic salts addition, time, and temperature. Results The degradation efficiency is mainly divided into two steps: 35.7% for maximum adsorption and 57.5% for photodegradation. Adsorption isotherm models confirmed that the process nature is chemisorption and appropriate Langmuir model, as well as to be a nonspontaneous and endothermic reaction according to the thermodynamic study. Adsorption constant during dark condition is smaller than typical adsorption equilibrium constant derived from the Langmuir–Hinshelwood kinetic model through photodegradation of MNZ that follows pseudo-first-order kinetics. Toxicity rates were reduced considerably after the photodegradation process to 88.21%, 79.84%, and 67.32% and 57.45%, 51.98%, and 43.87% by heamolytic and brine shrimp assays, respectively, for initial MNZ concentrations (20, 60, and 100 mg/L). Conclusion We significantly recommend using MgO NP as a promising catalyst in the photodegradation applications for other organic pollutants in visible light.

SUBMITTER: El Bouraie M

PROVIDER: S-EPMC7533914 | biostudies-literature | 2020 Jan

REPOSITORIES: biostudies-literature

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Project description:Silicon (Si) is suggested to be an important/essential nutrient for bone and connective tissue health. Silicon-substituted hydroxyapatite (Si-HA) has silicate ions incorporated into its lattice structure and was developed to improve attachment to bone and increase new bone formation. Here we investigated the direct adsorption of silicate species onto an HA coated surface as a cost effective method of incorporating silicon on to HA surfaces for improved implant osseointegration, and determined changes in surface characteristics and osteoblast cell adhesion. Plasma-sprayed HA-coated stainless steel discs were incubated in silica dispersions of different concentrations (0-42 mM Si), at neutral pH for 12 h. Adsorbed Si was confirmed by XPS analysis and quantified by ICP-OES analysis following release from the HA surface. Changes in surface characteristics were determined by AFM and measurement of surface wettability. Osteoblast cell adhesion was determined by vinculin plaque staining. Maximum Si adsorption to the HA coated disc occurred after incubation in the 6 mM silica dispersion and decreased progressively with higher silica concentrations, while no adsorption was observed with dispersions below 6 mM Si. Comparison of the Si dispersions that produced the highest and lowest Si adsorption to the HA surface, by TEM-based analysis, revealed an abundance of small amorphous nanosilica species (NSP) of ~1.5 nm in diameter in the 6 mM Si dispersion, with much fewer and larger NSP in the 42 mM Si dispersions. 29Si-NMR confirmed that the NSPs in the 6 mM silica dispersion were polymeric and similar in composition to the larger NSPs in the 42 mM Si dispersion, suggesting that the latter were aggregates of the former. Amorphous NSP adsorbed from the 6 mM dispersion on to a HA-coated disc surface increased the surface's water contact angle by 53°, whereas that adsorbed from the 42 mM dispersion decreased the contact angle by 18°, indicating increased and decreased hydrophobicity, respectively. AFM showed an increase in surface roughness of the 6 mM Si treated surface, which correlated well with an increase in number of vinculin plaques. These findings suggest that NSP of the right size (relative to charge) adsorb readily to the HA surface, changing the surface characteristics and, thus, improving osteoblast cell adhesion. This treatment provides a simple way to modify plasma-coated HA surfaces that may enable improved osseointegration of bone implants.

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Differentiation Between Metronidazole Residues Disposal by Using Adsorption and Photodegradation Processes Onto MgO Nanoparticles

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