Dataset Information

Atom Exchange Versus Reconstruction: (Ge_x As_4-x )^x- (x=2, 3) as Building Blocks for the Supertetrahedral Zintl Cluster [Au₆ (Ge₃ As)(Ge₂ As₂ )₃ ]³.

ABSTRACT: The Zintl anion (Ge₂ As₂ )^2- represents an isostructural and isoelectronic binary counterpart of yellow arsenic, yet without being studied with the same intensity so far. Upon introducing [(PPh₃ )AuMe] into the 1,2-diaminoethane (en) solution of (Ge₂ As₂ )^2- , the heterometallic cluster anion [Au₆ (Ge₃ As)(Ge₂ As₂ )₃ ]^3- is obtained as its salt [K(crypt-222)]₃ [Au₆ (Ge₃ As)(Ge₂ As₂ )₃ ]⋅en⋅2 tol (1). The anion represents a rare example of a superpolyhedral Zintl cluster, and it comprises the largest number of Au atoms relative to main group (semi)metal atoms in such clusters. The over

SUBMITTER: Pan F

PROVIDER: S-EPMC7540319 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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Dataset Information

Atom Exchange Versus Reconstruction: (Ge_x As_4-x )^x- (x=2, 3) as Building Blocks for the Supertetrahedral Zintl Cluster [Au₆ (Ge₃ As)(Ge₂ As₂ )₃ ]³.

OmicsDI is part of the ELIXIR infrastructure

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Dataset Information

Atom Exchange Versus Reconstruction: (Gex As4-x )x- (x=2, 3) as Building Blocks for the Supertetrahedral Zintl Cluster [Au6 (Ge3 As)(Ge2 As2 )3 ]3.

OmicsDI is part of the ELIXIR infrastructure

Tweets

Atom Exchange Versus Reconstruction: (Ge_x As_4-x )^x- (x=2, 3) as Building Blocks for the Supertetrahedral Zintl Cluster [Au₆ (Ge₃ As)(Ge₂ As₂ )₃ ]³.