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Thioallenoates in Catalytic Enantioselective [2+2]-Cycloadditions with Unactivated Alkenes.

ABSTRACT: The application of thioallenoates to catalytic enantioselective [2+2]-cycloadditions with unactivated alkenes is reported.In many cases, the thioallenoates examined exhibit superior reactivity and selectivity compared to the alkoxy analogs generally used in these cycloadditions.

SUBMITTER: Conner ML 

PROVIDER: S-EPMC7584306 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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Thioallenoates in Catalytic Enantioselective [2+2]-Cycloadditions with Unactivated Alkenes.

Conner Michael L ML   Wiest Johannes M JM   Brown M Kevin MK  

Tetrahedron 20190425 24

The application of thioallenoates to catalytic enantioselective [2+2]-cycloadditions with unactivated alkenes is reported.In many cases, the thioallenoates examined exhibit superior reactivity and selectivity compared to the alkoxy analogs generally used in these cycloadditions. ...[more]

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