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Novel BaTiO3-Based, Ag/Pd-Compatible Lead-Free Relaxors with Superior Energy Storage Performance.

ABSTRACT: Ceramic dielectrics are reported with superior energy storage performance for applications, such as power electronics in electrical vehicles. A recoverable energy density (Wrec) of ?4.55 J cm-3 with ? ? 90% is achieved in lead-free relaxor BaTiO3-0.06Bi2/3(Mg1/3Nb2/3)O3 ceramics at ?520 kV cm-1. These ceramics may be co-fired with Ag/Pd, which constitutes a major step forward toward their potential use in the fabrication of commercial multilayer ceramic capacitors. Compared to stoichiometric Bi(Mg2/3Nb1/3)O3-doped BaTiO3 (BT), A-site deficient Bi2/3(Mg1/3Nb2/3)O3 reduces the electrical heterogeneity of BT. Bulk conductivity differs from the grain boundary only by 1 order of magnitude which, coupled with a smaller volume fraction of conducting cores due to enhanced diffusion of the dopant via A-site vacancies in the A-site sublattice, results in higher breakdown strength under an electric field. This strategy can be employed to develop new dielectrics with improved energy storage performance.

SUBMITTER: Yang H

PROVIDER: S-EPMC7586291 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature

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Novel BaTiO3-Based, Ag/Pd-Compatible Lead-Free Relaxors with Superior Energy Storage Performance.

Yang Huijing H Lu Zhilun Z Li Linhao L Bao Weichao W Ji Hongfen H Li Jinglei J Feteira Antonio A Xu Fangfang F Zhang Yong Y Sun Huajun H Huang Zhichao Z Lou Weichao W Song Kaixin K Sun Shikuan S Wang Ge G Wang Dawei D Reaney Ian M IM

ACS applied materials & interfaces 20200921 39

Ceramic dielectrics are reported with superior energy storage performance for applications, such as power electronics in electrical vehicles. A recoverable energy density (Wrec) of ∼4.55 J cm-3 with η ∼ 90% is achieved in lead-free relaxor BaTiO3-0.06Bi2/3(Mg1/3Nb2/3)O3 ceramics at ∼520 kV cm-1. These ceramics may be co-fired with Ag/Pd, which constitutes a major step forward toward their potential use ...[more]

PMID: 32885648

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Project description:A simple hydrothermal route assisted by a triblock copolymer was used to synthesize Ag2O/Ag nanoparticles on a robotic support consists of functionalized MWCNTs and graphene composite (Ag2O/Ag/CNT-graphene). The composites together with the individual analog of Ag/CNT and Ag/graphene were characterized by means of XRD, TEM-SAED, N2 sorptiometry, Raman, FTIR, UV-Vis, and photoluminescence spectroscopy. These nanomaterials were then tested for the catalytic reduction of 4-nitrophenol (4-NP) to the technologically beneficial 4-aminophenol (4-AP). The Ag2O@Ag@CNT-graphene composite calcined at 400°C has shown fascinating reduction performances for 4-NP either in the dark (k = 0.014 s-1) or under visible light illumination (k = 0.039 s-1) in the presence of 5 mM NaBH4 compared to Ag/CNT (0.0112 s-1) and Ag/graphene (0.010 s-1) catalysts. This was chiefly because Ag2O@Ag@CNT-graphene comprises the highest pore volume (0.49 cm3/g) and involves three types of pores in the margin from 1.8 to 4.0 nm in front of only one modal type of pores for the rest of the catalysts and thus maximizes the adsorptive capacity of the reactants (4-NP and NaBH4). Moreover, the former composite exhibits the highest concentration of the Ag2O component as established by numerous techniques in addition to the cyclic voltammetry, proposing it's facile reaction with 4-NP along with the simultaneous transfer of surface hydrogen and electrons from NaBH4 ions to produce 4-AP. The promotion of the p-n junction evaluated using the Mott-schottky equation on Ag2O@Ag@CNT-graphene assisted by charges separation and surface plasmon resonance bands of Ag and Ag2O are found to be advantageous for 4-NP reduction. The latter composite delivers a specific capacitance of 355 F g-1 at 1.0 A g-1 exceeding those of Ag/CNT (230 F g-1) and Ag/graphene (185 F g-1). The EIS study establishes the high electronic conductivity of the metallic Ag and Ag2O moieties, low internal resistance of CNT-graphene as well as the marked ionic transfer facilitated by the composite porous nature.

Dataset Information

Novel BaTiO3-Based, Ag/Pd-Compatible Lead-Free Relaxors with Superior Energy Storage Performance.

Publications

Novel BaTiO<sub>3</sub>-Based, Ag/Pd-Compatible Lead-Free Relaxors with Superior Energy Storage Performance.

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