Ontology highlight
ABSTRACT:
SUBMITTER: Korvorapun K
PROVIDER: S-EPMC7589283 | biostudies-literature | 2020 Jul
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20200817 41
Ambient temperature ruthenium-catalyzed C-H arylations were accomplished by visible light without additional photocatalysts. The robustness of the ruthenium-catalyzed C-H functionalization protocol was reflected by a broad range of sensitive functional groups and synthetically useful pyrazoles, triazoles and sensitive nucleosides and nucleotides, as well as multifold C-H functionalizations. Biscyclometalated ruthenium complexes were identified as the key intermediates in the photoredox ruthenium ...[more]