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Photo-Induced Ruthenium-Catalyzed C-H Benzylations and Allylations at Room Temperature.


ABSTRACT: The ruthenium-catalyzed synthesis of diarylmethane compounds was realized under exceedingly mild photoredox conditions without the use of exogenous photocatalysts. The versatility and robustness of the ruthenium-catalyzed C-H benzylation was reflected by an ample scope, including multifold C-H functionalizations, as well as transformable pyrazoles, imidates and sensitive nucleosides. Mechanistic studies were indicative of a photoactive cyclometalated ruthenium complex, which also enabled versatile C-H allylations.

SUBMITTER: Struwe J 

PROVIDER: S-EPMC9293244 | biostudies-literature |

REPOSITORIES: biostudies-literature

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