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Water-soluble host-guest complexes between fullerenes and a sugar-functionalized tribenzotriquinacene assembling to microspheres.


ABSTRACT: A sugar-functionalized water-soluble tribenzotriquinacene derivative bearing six glucose residues, TBTQ-(OG) 6 , was synthesized and its interaction with C60 and C70-fullerene in co-organic solvents and aqueous solution was investigated by fluorescence spectroscopy and ultraviolet-visible spectroscopy. The association stoichiometry of the complexes TBTQ-(OG) 6 with C60 and TBTQ-(OG) 6 with C70 was found to be 1:1 with binding constants of K a = (1.50 ± 0.10) × 105 M-1 and K a = (2.20 ± 0.16) × 105 M-1, respectively. The binding affinity between TBTQ-(OG) 6 and C60 was further verified by Raman spectroscopy. The geometry of the complex of TBTQ-(OG) 6 with C60 deduced from DFT calculations indicates that the driving force of the complexation is mainly due to the hydrophobic effect and to host-guest ?-? interactions. Hydrophobic surface simulations showed that TBTQ-(OG) 6 and C60 forms an amphiphilic supramolecular host-guest complex, which further assembles to microspheres with diameters of 0.3-3.5 ?m, as determined by scanning electron microscopy.

SUBMITTER: Liu SY 

PROVIDER: S-EPMC7590625 | biostudies-literature | 2020

REPOSITORIES: biostudies-literature

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Water-soluble host-guest complexes between fullerenes and a sugar-functionalized tribenzotriquinacene assembling to microspheres.

Liu Si-Yuan SY   Wang Xin-Rui XR   Li Man-Ping MP   Xu Wen-Rong WR   Kuck Dietmar D  

Beilstein journal of organic chemistry 20201014


A sugar-functionalized water-soluble tribenzotriquinacene derivative bearing six glucose residues, <b>TBTQ-(OG)</b> <b><sub>6</sub></b> , was synthesized and its interaction with C<sub>60</sub> and C<sub>70</sub>-fullerene in co-organic solvents and aqueous solution was investigated by fluorescence spectroscopy and ultraviolet-visible spectroscopy. The association stoichiometry of the complexes <b>TBTQ-(OG)</b> <b><sub>6</sub></b> with C<sub>60</sub> and <b>TBTQ-(OG)</b> <b><sub>6</sub></b> with  ...[more]

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