Capillary Imbibition of Binary Fluid Mixtures in Nanochannels.
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ABSTRACT:
SUBMITTER: Hulikal Chakrapani T
PROVIDER: S-EPMC7594272 | biostudies-literature | 2020 Oct
REPOSITORIES: biostudies-literature
Publications
Capillary Imbibition of Binary Fluid Mixtures in Nanochannels.
Hulikal Chakrapani Thejas T den Otter Wouter K WK
Langmuir : the ACS journal of surfaces and colloids 20201013 42
Many-body Dissipative Particle Dynamics (MDPD) simulations of binary fluid mixtures imbibing cylindrical nanochannels reveal a strong segregation of fluids differing in their affinities to the pore walls. Surprisingly, the imbibition front furthest into the channel is highly enriched in the fluid with the lower affinity for the walls, i.e., the fluid less prone to enter the pore. This effect is caused by the more-wetting fluid forming a monolayer covering the walls of the pore, while the lesser- ...[more]
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