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A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes.

ABSTRACT: We report on the synthesis of an alkane-soluble Zintl cluster, [?4-Ge9(Hyp)3]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst.

SUBMITTER: Townrow OPE

PROVIDER: S-EPMC7596751 | biostudies-literature | 2020 Oct

REPOSITORIES: biostudies-literature

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A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes.

Townrow Oliver P E OPE Chung Cheuk C Macgregor Stuart A SA Weller Andrew S AS Goicoechea Jose M JM

Journal of the American Chemical Society 20201014 43

We report on the synthesis of an alkane-soluble Zintl cluster, [η4-Ge9(Hyp)3]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and cis-cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst. ...[more]

PMID: 33052653

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