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A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes.
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ABSTRACT:
SUBMITTER: Townrow OPE
PROVIDER: S-EPMC7596751 | biostudies-literature | 2020 Oct
REPOSITORIES: biostudies-literature
Publications
A Neutral Heteroatomic Zintl Cluster for the Catalytic Hydrogenation of Cyclic Alkenes.
Journal of the American Chemical Society 20201014 43
We report on the synthesis of an alkane-soluble Zintl cluster, [η<sup>4</sup>-Ge<sub>9</sub>(Hyp)<sub>3</sub>]Rh(COD), that can catalytically hydrogenate cyclic alkenes such as 1,5-cyclooctadiene and <i>cis</i>-cyclooctene. This is the first example of a well-defined Zintl-cluster-based homogeneous catalyst. ...[more]